2018年3月
Flash generation and borylation of 1-(trifluoromethyl)vinyllithium toward synthesis of alpha-(trifluoromethyl)styrenes
JOURNAL OF FLUORINE CHEMISTRY
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- 巻
- 207
- 号
- 開始ページ
- 72
- 終了ページ
- 76
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1016/j.jfluchem.2018.01.004
- 出版者・発行元
- ELSEVIER SCIENCE SA
Thermally unstable (3,3,3-trifluoroprop-1-en-2-yl)lithium was generated by lithiation of 2-bromo-3,3,3-tri-fluoroprop-1-ene and successively underwent borylation in a flow microreactor system. Direct use of the 1-(trifluoromethyl)vinylborate thus formed for the Suzuki-Miyaura coupling in a batch system afforded alpha-(tri-fluoromethyl)styrenes in high yields.
- リンク情報
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- DOI
- https://doi.org/10.1016/j.jfluchem.2018.01.004
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201802256218187595
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000425557400010&DestApp=WOS_CPL
- URL
- http://jglobal.jst.go.jp/public/201802256218187595
- ID情報
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- DOI : 10.1016/j.jfluchem.2018.01.004
- ISSN : 0022-1139
- eISSN : 1873-3328
- J-Global ID : 201802256218187595
- Web of Science ID : WOS:000425557400010