2010年6月
Diastereodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate Tethered to Cellulose Scaffold
JOURNAL OF ORGANIC CHEMISTRY
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- 巻
- 75
- 号
- 12
- 開始ページ
- 4307
- 終了ページ
- 4310
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1021/jo100596n
- 出版者・発行元
- AMER CHEMICAL SOC
A series of anthracenecarboxylate(AC)-appended 2,3-di-O-methylcelluloses (AC-Cells) of varying degrees of substitution (DS) were synthesized to examine their photochirogenic behavior under a variety of conditions. The product distribution and enantiomeric excess of the cyclodimers obtained upon photoirradiation and the subsequent saponification were critical functions of the DS and conversion, for which a conformational change of the flexible polymer backbone is likely to be responsible.
- リンク情報
- ID情報
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- DOI : 10.1021/jo100596n
- ISSN : 0022-3263
- Web of Science ID : WOS:000278560700044