MISC

2008年11月

Clathrate Hydrate Formation from Cyclopentane-in-Water Emulsions

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
  • Masahiro Nakajima
  • ,
  • Ryo Ohmura
  • ,
  • Yasuhiko H. Mori

47
22
開始ページ
8933
終了ページ
8939
記述言語
英語
掲載種別
DOI
10.1021/ie800949k
出版者・発行元
AMER CHEMICAL SOC

This paper reports the experimental examinations of hydrate-forming cyclopentane-in-water emulsions as potential thermal energy storage media for air-conditioning systems. It was demonstrated that an adequately compounded cyclopentane/water/surfactant mixture formed a stable emulsion with the aid of continuous agitation and, through its cooling to similar to 2 degrees C, turned into a bulky mass of granular hydrate crystals. The behavior of the hydrate formation was investigated by varying the amount and composition of the surfactant (or surfactant mixture) in the sample cyclopentane/water/surfactant mixture from run to run in order to determine the appropriate preparation of the mixture for efficient hydrate formation. Also performed were measurements of the effective heat of dissociation for the granular hydrate products obtained in the above hydrate-forming experiments. The measurements showed that the effective heat of dissociation can be as high as similar to 93% of the intrinsic heat of dissociation of cyclopentane hydrate crystals, thereby indicating a sufficient potential of the cyclopentane-in-water emulsions as thermal energy storage media.

リンク情報
DOI
https://doi.org/10.1021/ie800949k
CiNii Articles
http://ci.nii.ac.jp/naid/80020031682
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000260889000049&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/ie800949k
  • ISSN : 0888-5885
  • CiNii Articles ID : 80020031682
  • Web of Science ID : WOS:000260889000049

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