2020年8月12日
Total Synthesis of Terpioside B
Chemistry - A European Journal
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- 巻
- 26
- 号
- 45
- 開始ページ
- 10222
- 終了ページ
- 10225
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/chem.202002878
- 出版者・発行元
- Wiley-VCH
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The first total synthesis of terpioside B (1) has been accomplished. Key steps include the stereoselective installments of a set of challenging 1,2-cis-glycosidic linkages. Thus, α(1,4)-linked d-galactoside was effectively constructed from a 1,2-anhydrogalactose donor and an unprotected 1,6-anhydrogalactose acceptor by using a boron-mediated aglycon delivery (BMAD) method. In addition, α-l-fucofuranosides were stereoselectively and simultaneously constructed by remote group-assisted 1,2-cis-α-stereoselective glycosylations.
- リンク情報
- ID情報
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- DOI : 10.1002/chem.202002878
- ISSN : 0947-6539
- PubMed ID : 32567165