2000年1月
Fading of azo dyes with sodium sulphite
JOURNAL OF THE SOCIETY OF DYERS AND COLOURISTS
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- 巻
- 116
- 号
- 1
- 開始ページ
- 16
- 終了ページ
- 22
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- 出版者・発行元
- SOC DYERS COLOURISTS
The fading behaviour of a variety of naphthol azo dyes with an excess of sodium sulphite was investigated spectrophotometrically at 30 degrees C in the pH range from 3 to 10. The fading occurred most efficiently under neutral conditions. The azo dyes employed were grouped distinctly into the following three types on basis of the observed spectroscopic characteristics: addition type (A-type), in which the dyes had relatively faster rates had isosbestic points at near 440 nm; reduction type (R-type), in which the dyes had slower fading rates and no clear isosbestic point; and no reaction type (N-type), in which the dyes showed no fading under the experimental conditions. The results suggested that the fading of the azo dyes with sodium sulphite occurred through a Michael addition of a sulphite ion to a conjugate active enone moiety in the hydrazone tautomer (A-type), or to a conjugate iminone moiety in the same tautomer (R-type).
- リンク情報
- ID情報
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- ISSN : 0037-9859
- Web of Science ID : WOS:000084689700004