1992年6月
CORRELATION AMONG THE TRANSITION AND MELTING TEMPERATURES AND DIELECTRIC PARAMETERS IN SOME FAST IONIC CONDUCTORS
SOLID STATE COMMUNICATIONS
- 巻
- 82
- 号
- 9
- 開始ページ
- 705
- 終了ページ
- 710
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/0038-1098(92)90065-H
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
Three correlationships are established among the optical dielectric constant epsilon(infinity), Szigeti effective charge e(s)*, transition temperature T(c), melting temperature T(m), and optical phonon frequency for many cubic fast ionic conductors. These relations suggest an intense influence of electronic energy state near the band gap to the origin of fast ionic conduction, dominant contribution of short-range or long-range forces to the mobile ion below T(c) or to the cage ion above T(c). A curious temperature dependence for epsilon(infinity) and e(s)* values is also interpreted by considering anharmonic dynamical effective charge.
- リンク情報
- ID情報
-
- DOI : 10.1016/0038-1098(92)90065-H
- ISSN : 0038-1098
- CiNii Articles ID : 80006551347
- Web of Science ID : WOS:A1992JA64900013