1998年2月
Reactions of a spiro trisilane with palladium complexes: Synthesis and structure of tris(organosilyl)CpPdIV and Bis(organosilyl)(mu-organosilylene)Pd-2(II) complexes
ORGANOMETALLICS
- ,
- ,
- ,
- ,
- 巻
- 17
- 号
- 4
- 開始ページ
- 495
- 終了ページ
- 497
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1021/om9710778
- 出版者・発行元
- AMER CHEMICAL SOC
1,1,6,6-Tetramethyl-1,5,6-trisilaspiro[4.4]nonane was reacted with bis(tert-alkyl isocyanide)palladium(0) and (eta(5)-cyclopentadienyl)(eta(3)-allyl)palladium(II) through oxidative addition of the Si-Si bonds to afford a dinuclear palladium(II) complex and a stable palladium(IV) complex, respectively. The Latter palladium(IV)-complex-catalyzed ring-opening polymerization of 1,1,2,2-tetramethyl-1,2-disilacyclopentane gives organosilicon polymers with high molecular weight.
- リンク情報
- ID情報
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- DOI : 10.1021/om9710778
- ISSN : 0276-7333
- CiNii Articles ID : 80010173740
- Web of Science ID : WOS:000072154500003