2012年2月
Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- ,
- ,
- 巻
- 134
- 号
- 8
- 開始ページ
- 3699
- 終了ページ
- 3702
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ja3002953
- 出版者・発行元
- AMER CHEMICAL SOC
Pyridine undergoes addition of pinacolborane at 50 degrees C in the presence of a rhodium catalyst, giving N-boryl-1,2-dihydropyridine in a high yield. The selective 1,2-hydroboration also takes place in the reactions of substituted pyridines. In the reaction of 3-substituted pyridines, 3-substituted N-boryl-1,2-dihydropyridines are formed regioselectively.
- リンク情報
- ID情報
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- DOI : 10.1021/ja3002953
- ISSN : 0002-7863
- Web of Science ID : WOS:000301161600022