HIROSE Keiji

J-GLOBAL         Last updated: Dec 5, 2019 at 04:39
 
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Name
HIROSE Keiji
Alternative names
Keiji Hirose
E-mail
hirosechem.es.osaka-u.ac.jp
Affiliation
Osaka University
Section
Graduate School of Engineering Science Department of Materials Engineering Science
Job title
Associate Professor
Degree
Doctor of Science(Osaka University)
Research funding number
10252628
ORCID ID
https://orcid.org/0000-0001-9604-9754

Research Areas

 
 

Academic & Professional Experience

 
1988
 - 
1993
Mitsui Petrochemical Industry LTD.,
 
 
   
 
Research Chemist
 
1993
 - 
2000
Osaka University,
 
 
   
 
Research Associate
 
2000
   
 
- Osaka University,
 

Education

 
 
 - 
1988
Graduate School, Division of Natural Science, Osaka University
 
 
 - 
1983
Faculty of Science, Osaka University
 

Awards & Honors

 
2009
HGCS Japan Award of Excellence 2009
 

Published Papers

 
Iritani K, Takeda H, Kather M, Yokoi M, Moeglen M, Ikeda M, Otsubo Y, Ozawa Y, Tahara K, Hirose K, De Feyter S, Tobe Y
Langmuir : the ACS journal of surfaces and colloids      Nov 2019   [Refereed]
Iritani Kohei, Ikeda Motoki, Yang Anna, Tahara Kazukuni, Anzai Masaru, Hirose Keiji, De Feyter Steven, Moore Jeffrey S., Tobe Yoshito
LANGMUIR   34(21) 6036-6045   May 2018   [Refereed]
Hirose Keiji, Ukimi Masaya, Ueda Shota, Onoda Chie, Kano Ryohei, Tsuda Kyosuke, Hinohara Yuko, Tobe Yoshito
SYMMETRY-BASEL   10(1)    Jan 2018   [Refereed]
Iritani Kohei, Ikeda Motoki, Yang Anna, Tahara Kazukuni, Hirose Keiji, Moore Jeffrey S., Tobe Yoshito
LANGMUIR   33(43) 12453-12462   Oct 2017   [Refereed]
DEVELOPMENT OF CROWN ETHER BASED ROTAXANES HAVING CHIRALITY SPECIFIC TO ROTAXANE STRUCTURE
Hirose Keiji
SYMMETRY-CULTURE AND SCIENCE   28(2) 191-194   2017   [Refereed]
Hirose Keiji, Okada Shizuka, Umezaki Shota, Young Philip G., Tobe Yoshito
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY   331 184-189   Dec 2016   [Refereed]
Iritani Kohei, Tahara Kazukuni, Hirose Keiji, De Feyter Steven, Tobe Yoshito
CHEMICAL COMMUNICATIONS   52(100) 14419-14422   Dec 2016   [Refereed]
Tahara Kazukuni, Gotoda Jun, Carroll Calden N., Hirose Keiji, De Feyter Steven, Tobe Yoshito
CHEMISTRY-A EUROPEAN JOURNAL   21(18) 6806-6816   Apr 2015   [Refereed]
Young Philip G., Hirose Keiji, Tobe Yoshito
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   136(22) 7899-7906   Jun 2014   [Refereed]
Molecular brake rotaxane systems composed of a dianthrylethane-based macrocycle as the ring component and a dumbbell shaped secondary ammonium as the axle component controlled by light and heat
Hirose Keiji
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   246    Sep 2013   [Refereed]
廣瀬敬治
薬学図書館   58(1) 62-72   Jan 2013
Hirose Keiji, Miura Shintaro, Senda Yui, Tobe Yoshito
CHEMICAL COMMUNICATIONS   48(48) 6052-6054   Jun 2012   [Refereed]
Hirose Keiji, Yachi Yuka, Tobe Yoshito
CHEMICAL COMMUNICATIONS   47(23) 6617-6619   Jun 2011   [Refereed]
Chun Kyungmin, Kim Tae Hyun, Lee One-Sun, Hirose Keiji, Chung Taek Dong, Chung Doo Soo, Kim Hasuck
ANALYTICAL CHEMISTRY   78(21) 7597-7600   Nov 2006   [Refereed]
UCHIDA Sachie, KOMATSU Yuichiro, SATOH Hitomi, YAJIMA Setsuko, KIMURA Keiichi, TOBE Yoshito, SASAKI Shin-ichi, MIZUNO Masaaki, WATANABE Yohei, HIROSE Keiji
BUNSEKI KAGAKU   53(9) 943-952   Sep 2004
We desinged seven neutral carriers for hydrophilic anion sensors : four compounds containing one thiourea group and dendritic benzyl ether derivatives, two compounds containing three or four thiourea groups, and a cyclic compound containing three ...
Sawada M, Takai Y, Yamada H, Yoshikawa M, Arakawa R, Tabuchi H, Takada M, Tanaka J, Shizuma M, Hirose K, Fukuda K, Tobe Y
European journal of mass spectrometry (Chichester, England)   10(1) 27-37   2004   [Refereed]
UESHIGE T., NISHIOKA R., NAKAMURA T., HIROSE K., TOBE Y.
Chromatography : journal of separation and detection sciences = クロマトグラフィー : 分離・検出科学   21(4) 368-369   Oct 2000
NISHIOKA R., UESHIGE T., NAKAMURA T., HIROSE K., TOBE Y.
Chromatography : journal of separation and detection sciences = クロマトグラフィー : 分離・検出科学   21(4) 294-295   Oct 2000
SAWADA Masami, HAGITA Kouji, IMAMURA Hiroyuki, TABUCHI Hiroyuki, YODOYA Shinya, UMEDA Maki, TAKAI Yoshio, YAMADA Hitoshi, YAMAOKA Hiroshi, HIROSE Keiji, TOBE Yoshito, TANAKA Toshikazu, TAKAHASHI Shigetoshi
Journal of the Mass Spectrometry Society of Japan   48 (5), 323-332/,(5) 323-332   Oct 2000
Chiral recognition ability of crown ether hosts toward organic amine salt guests has been evaluated using the FAB mass spectrometry coupled with our enantiomer-labeled guest method for the total 97 sets of chiral host-guest complexations. The host...
Synthesis of Azophenolic crown Ethers of Cs Symmetry incorporaingcis-1-Phenylcyclohexane -1,2-diol Residues as a Steric Barrier and Diastereotopic Face Selectivity in Complexation of Amines by their Diastereolopic Faces
J.Chem.Soc,Perkin Trans, I   1429   1995
Preparation and Enantiomer Recognition Behaviour of Azophenolic Crown Ethers containing cis-Cyclohexane-1,2-diol as the Chiral Centre
J. Chem. Soc. , Perkin Trans. I   213   1995
Lipase YS-catalyzed Acylation of Alcohols a Predictive Active Site Model for Lipase YS to Identify which Enantiomer of a Primary or a Secondary Alcohol Reacts Faster in this Acylation
J. Chem. Soc., Perkin Trans. I   1253   1994
J. Molecular Catalysis   73,271/,    1992

Misc

 
入谷康平, 入谷康平, 鵜野裕基, 国元一樹, 田原和邦, 田原和邦, 廣瀬敬治, 戸部義人, 戸部義人
高分子学会予稿集(CD-ROM)   67(2) ROMBUNNO.1K05   Aug 2018
廣瀬敬治, 浮見雅哉, 上田将太, 小野田知恵, 加納椋平, 津田恭祐, 日野原祐子, 魚井清香, 河合真, 戸部義人
ホスト-ゲスト・超分子化学シンポジウム講演要旨集   16th 127   Jun 2018
久保有輝, 田原一邦, 田原一邦, 田原一邦, HIRSCH Brandon E., 廣瀬敬治, DE FEYTER Steven, 戸部義人, 戸部義人
日本化学会春季年会講演予稿集(CD-ROM)   98th ROMBUNNO.2F5‐29   Mar 2018
廣瀬敬治, 小野田知恵, 高林亮, 岡田静, 戸部義人
日本化学会春季年会講演予稿集(CD-ROM)   98th ROMBUNNO.1PA‐109   Mar 2018
辻孝史, 田原一邦, 田原一邦, 廣瀬敬治, 戸部義人, 戸部義人
基礎有機化学討論会要旨集   28th 146   Sep 2017
入谷康平, 池田元城, 田原一邦, 廣瀬敬治, 戸部義人
ホスト-ゲスト・超分子化学シンポジウム講演要旨集   15th 33   Jun 2017
廣瀬敬治, 上田将太, 梅崎将太, 津田恭佑, 戸部義人
日本化学会春季年会講演予稿集(CD-ROM)   97th ROMBUNNO.2PC‐158   Mar 2017
廣瀬敬治, 梅崎将太, 加納椋平, YOUNG Philip Geoffrey, 戸部義人
ホスト・ゲスト化学シンポジウム講演要旨集   14th 87   Jun 2016
廣瀬敬治, 加納椋平, YOUNG Philip G., 戸部義人
日本化学会春季年会講演予稿集(CD-ROM)   96th ROMBUNNO.1F4‐39   Mar 2016
廣瀬敬治, 梅崎将太, 加納椋平, YOUNG Philip G., 戸部義人
日本化学会春季年会講演予稿集(CD-ROM)   96th ROMBUNNO.3PB‐119   Mar 2016
廣瀬敬治, 梅崎将太, 加納椋平, YOUNG P. G., 戸部義人
日本化学会講演予稿集   95th(4) 1019   Mar 2015
廣瀬敬治, 津田恭佑, 古谷創, 日野原裕子, 戸部義人
日本化学会講演予稿集   94th(4) 1170   Mar 2014
廣瀬敬治, 高林亮, 津田恭佑, 岡田静, YOUNG Philip G., 戸部義人
日本化学会講演予稿集   94th(4) 1537   Mar 2014
廣瀬敬治, 加納椋平, YOUNG P. G., 戸部義人
日本化学会講演予稿集   94th(4) 1171   Mar 2014
草部浩一, 廣瀬敬治, 戸部義人
日本物理学会講演概要集   68(2) 441   Aug 2013
YOUNG Philip G., 加納椋平, 廣瀬敬治, 戸部義人
基礎有機化学討論会要旨集   24th 474   Aug 2013
Kusakabe Koichi, Hirose Keiji, Tobe Yoshito
Meeting Abstracts of the Physical Society of Japan   68(0)    2013
廣瀬敬治, 津田恭佑, 古谷創, 日野原祐子, 戸部義人
日本化学会講演予稿集   92nd(4) 1658   Mar 2012
靜間基博, 安達廣, 浅野芳織, 松崎剛, 佐藤博文, 鈴木健之, 廣瀬敬治, 戸部義人, 川崎英也, 荒川隆一, 小野大助
質量分析総合討論会講演要旨集   59th 101   Sep 2011
廣瀬敬治, 岡田静, 戸部義人
日本化学会講演予稿集   91st(4) 1598   Mar 2011
Hirose Keiji, Okada Shizuka, Tobe Yoshito
Abstracts of Papers: Host-Guest Chemistry Symposium   2011(0) 70-70   2011
An anthracene-based photochromic crown ether type ring molecule was designed and synthesized as a key component for molecular brakes with rotaxane-structure. The cavity-size of the ring was changed reversibly and substantially by photo dimerizatio...
Hirose Keiji, Furutani Hajime, Tobe Yoshito
Abstracts of Papers: Host-Guest Chemistry Symposium   2010(0) 105-105   2010
廣瀬敬治, 岡田静, 古谷創, 石橋和明, 戸部義人
基礎有機化学討論会要旨集   20th 280   Sep 2009
Hirose Keiji, Okada Shizuka, Ishibashi Kazuaki, Shiba Yoshinobu, Tobe Yoshito
Abstracts of Papers: Host-Guest Chemistry Symposium   2009(0) 28-28   2009
Hirose Keiji, Okada Shizuka, Furutani Hajime, Ishibashi Kazuaki, Tobe Yoshito
Abstracts of Symposium on Physical Organic Chemistry   2009(0) 162-162   2009
We developed a new molecular brake system in which a rocking motion of a rotaxane is stopped. This brake system operates by inputting physical stimuli into an anthracene-based ring component. Photodimerization and thermal reversion of the anthrace...
廣瀬敬治, 矢地佑佳, 戸部義人
日本化学会講演予稿集   88th(2) 1467   Mar 2008
田原一邦, LEI Shengbin, MAMDOUH Wael, 山口結衣, 雲林院宏, 園田素啓, 廣瀬敬治, DE SCHRYVER Frans, DE FEYTER Steven, 戸部義人
日本化学会講演予稿集   88th(2) 1367   Mar 2008
Hirose Keiji, Nakamura Yamato, Tobe Yoshito
Abstracts of Papers: Host-Guest Chemistry Symposium   2008(0) 104-104   2008
Hirose Keiji Hirose, Yachi Yuka, Tobe Yoshito
Abstracts of Papers: Host-Guest Chemistry Symposium   2008(0) 12-12   2008
Ikuta Kazuhiro, Hirose Keiji, Nakamura Yamato, Tobe Yoshito
Abstracts of Symposium on Physical Organic Chemistry   2008(0) 3-3   Sep 2008
Certain rotaxanes can be decomposed via a deslipping processe by which a ring slips over a stopper of a dumbbell. Deslipping reaction rates are affected not only by size of a stopper relative to the ring but also by other structural factors such a...
廣瀬敬治, 中村大和, 戸部義人
日本化学会講演予稿集   87th(2) 1099   Mar 2007
山口結衣, 市川智之, 園田素啓, 田原一邦, 廣瀬敬治, 戸部義人
日本化学会講演予稿集   87th(2) 1151   Mar 2007
廣瀬敬治, 西原啓二, 原田直樹, 荒木正美, 戸部義人
日本化学会講演予稿集   87th(2) 1098   Mar 2007
Hirose keiji, Nakamura Yamato, Takano Hirokazu, Tobe Yoshito
Abstracts of Symposium on Physical Organic Chemistry   57(0) 18-18   Sep 2007
Two series of rotaxanes, which consist of axles with amide group and rings with phenol moiety, have been synthesized by aminolysis of prerotaxanes. The kinetics of the deslipping reaction of these rotaxnes were studied. The deslipping of the rotax...
Hirose Keiji, Hinohara Yuko, Nakamura Yamato, Tobe Yoshito
Abstracts of Symposium on Physical Organic Chemistry   37(0) 112-112   Oct 2007
A rotaxane has a mechanically interlocked architecture consisting of a dumbbell-shaped component that is threaded through a ring component. Some of rotaxanes consisting of achiral dumbbell-shaped components and achiral ring components can be chira...
廣瀬敬治, 西原啓二, 原田直樹, 荒木正美, 戸部義人
日本化学会講演予稿集   86th(2) 1230   Mar 2006
廣瀬敬治, JIN Yongzhu, 中村崇, 西岡亮太, 上重哲郎, 戸部義人
日本化学会講演予稿集   86th(1) 636   Mar 2006
廣瀬敬治, 三浦新太郎, 仙田結, 戸部義人
日本化学会西日本大会講演予稿集   2005 119-120   Oct 2005
廣瀬敬治, 西原啓二, 原田直樹, 増田大輔, 荒木正美, 戸部義人
基礎有機化学連合討論会予稿集   18th(0) 243-132   Oct 2006
Previously, we have reported a rotaxane synthesis with high selectivity via aminolysis of a prerotaxane consisting of a crown ether ring component and a bulky stopper unit. Crown ether structure of the prerotaxane is essential for the selective fo...
Hirose Keiji, Harada Naoki, Masuda Daisuke, Araki Masami, Tobe Yoshito
Abstracts of Symposium on Physical Organic Chemistry   17(0) 333-333   2004
メタシクロファン型フェノール性クラウンエーテル輪分子と、かさ高いカルボン酸であるストッパー成分から成るリング・ストッパー成分結合型プレロタキサンエステルにかさ高いアミンを作用させると、エステル‐アミド交換反応が起こり選択的にロタキサンを合成できる。今回我々は、本ロタキサン合成反応について、クラウンエーテル環のアミノリシス反応に及ぼす効果を調べるとともに、輪分子の大きさの異なるプレロタキサンを用いてロタキサン合成を試みた。また、キラル置換基を導入したプレロタキサンとキラルアミンとのアミノリシ...
The Development of Polypropylene Production
56,629/,    1992
Polyethylene Production Method with Ziegler Catalyst
19,40/,    1992
Preparation and enantiomer recognition on behaviour ofazophenolic crown ethers containing cis-cyclohexane-1,2-diol as the Chiral Centre
J.Chem.Soc Perkin Trans, I   213   1995
Preparation and enantiomer recognition behaviour of azophcnolic crown ethers containing cis-1-,2-diol as the Chiral subunit and 2,4- dinitrophenylazophenol as the chromophore
J.Chem.Soc.Perkin trans,I   383   1995
Lipase-catalyzed Enantioselective Alcoholysis of Enol Acetates : Optical Resolution of Ketones and Aldehydes using Lipases in Organic Solvents
Enantiomer   1 219   1996
Preparation and Enantiomer Recognition Behavior of Azophenolic Crown Ethers containing cis-Cyclohexane-1, 2-diol as the Chiral Subunit and 2, 4-Dinitrophenylazophenol as the Chromophore
J. Chem. Soc., Perkin Trans. I   383   1996
Preparation of Optically Active Azophenolic Crown Ethers Containing 1-Phenylethane-1,2-Diol and 2,4-Dimethyl-3-Oxapentane-1,5-Diol as a Chiral Subunits : Temperature-dependent Enantiomer Selectivity in Complexation with Chiral Amines
J. Chem. Soc. , Perkin Trans. 1   3227   1997
Temperature Dependent Inversion of Enantiomer Selectivity in the Complexation of Optically Active Azophenolic Crown Ethers Containing Alkyl Substituents as Chiral Barriers with Chiral Amines
J. Chem. Soc. , Perkin Trans. 2   1649   1997
Tetrahedron Lett.   38(27) 4791-4794   1997
Koichiro NAEMURA, Kazuhisa MATSUNAGA, Junichi FUJI, Kazuko OGASAHARA, Yasushi NISHIKAWA, Keiji HIROSE, Yoshito TOBE
Analytical Science   14(1) 175-182   1998
Chiral Amino Acid Recognition Detected by Electrospray Ionization(ESI)and Fast Atom Bombardment(FAB)Mass Spectrometry(MS)Coupled with the Enantiomer Labelled(EL)Guest Method
J. Chem. Soc. , Perkin Trans. 2   701   1998
J. Incl. Phenom. Macro   39(3/4) 193-209   2001
Chiral recognizable host-guest interactions detected by fast-atom bombardment mass spectrometry: application to the enantiomeric excess determination of primary amines
Eur. J. of Mass Spec.   7 447-459   2001
Chapter 2, "Determination of Binding Constants", in "Analytical Methods in Supramolecular Chemistry"
Wiley-VCH      2007
ADVANCED FUNCTIONAL MATERIALS   16 (12): 1549-1554    2006
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY   39, 193-209    2001
CHEMISTRY-A EUROPEAN JOURNAL   14 (11) 3427-3433    2008
Enantioselective Complexation of Pho nolic Crown Ethers with Chiral Aminoethanol Derivatives : Effects of Substituents of Aromatic Rings of Hosts and Guests on Complexation
2, 1984-1993    2000
Creat the Brown Motion with Bias
Kagaku      2003
Chiral Amino Acid Recognition Detected by Electrospray Ionization and Fast Atom Bombardment Mass Spectrometry Coupled with the Enantiomer-Labeled Guest Method.
2, 701-710    1998

Books etc

 
Master Guide
Kagaku Dojin   2010   

Works

 
Development of moleculare recognition type chiral column
1999 - 2000
Improvement of molecular recognition type chiral column
2000 - 2001
Chiral recognition in NMR spectroscopy using crown ethers and their ytterbium(III) complexes
2002 - 2003

Research Grants & Projects

 
Study on Molecular Recognition
Synthetic Application of Biocatalysts
Syntheses of Artificial Receptor bearing novel basic skelton.

Patents

 
エチレン・α-オレフィンランダム共重合体の製造方法
特許出願昭63—330577
Chiral Senser
特許出願2002-239777
α-オレフィン系ランダム共重合体の製造方法
特許出願昭63—330578
環状オレフィン系共重合体の製造方法
特許出願昭63—330579
オレフィン重合用触媒成分およびオレフィンの重合方法
特許出願昭63—330580