Papers

Peer-reviewed
2010

Biosorption of Lanthanides from Aqueous Solutions Using Pretreated Buccinum tenuissimum Shell Biomass

BIOINORGANIC CHEMISTRY AND APPLICATIONS
  • Yusuke Koto
  • ,
  • Naoki Kano
  • ,
  • Yudan Wang
  • ,
  • Nobuo Sakamoto
  • ,
  • Hiroshi Imaizumi

Volume
2010
Number
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1155/2010/804854
Publisher
HINDAWI PUBLISHING CORPORATION

Biosorption experiment from aqueous solutions containing known amount of rare earth elements (REEs) using pre-treated Buccinum tenuissimum shell was explored to evaluate the efficiency of shell biomass as sorbent for REEs. In this work, four kinds of sieved shell samples: (a) "Ground original sample", (b) "Heat-treatment (480 degrees C, 6 hours) sample", (c) "Heat-treatment (950 degrees C, 6 hours) sample" and (d) "Heat-treatment (950 degrees C, 6 hours) and water added sample" were used. Furthermore, to confirm the characteristics of the shell biomass, the crystal structure, the surface morphology, and the specific surface area of these shell samples were determined. Consequently, the following matters have been mainly clarified. (1) The crystal structure of the shell biomass was transformed from aragonite (CaCO(3)) into calcite (CaCO(3)) phase by heat-treatment (480 degrees C, 6 hours); then mainly transformed into calcium oxide (CaO) by heat-treatment (950 degrees C, 6 hours), and calcium hydroxide (Ca(OH)(2)) by heat-treatment (950 degrees C, 6 hours) and adding water. (2) The shell biomass showed excellent sorption capacity for lanthanides. (3) Adsorption isotherms using the shell biomass can be described by Langmuir and Freundlich isotherms satisfactorily for lanthanides except "heat-treatment (950 degrees C, 6 hours) sample". (4) Shell biomass (usually treated as waste material) can be an efficient sorbent for lanthanides in future.

Link information
DOI
https://doi.org/10.1155/2010/804854
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000285594200001&DestApp=WOS_CPL
ID information
  • DOI : 10.1155/2010/804854
  • ISSN : 1565-3633
  • Web of Science ID : WOS:000285594200001

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