We previously reported that cinnamoyl-modified bezpybox undergoes photodimeization in the presence of secondary ammonium cations as a template. Now we prepareed ditopic bezpybox ligand possessing two cinnamoyl moieties (1-a) in the spacer. The dimeric template 2N3C provided the dimmer chiefly. And the trimeric template 3N3C yielded trimer or higher oligomers. The degree of polymerization of 1-a may depend on the number of dialkylammonium moieties in the template.