論文

査読有り
1994年7月

CIDEP MEASUREMENT IN THE L-BAND MICROWAVE FREQUENCY REGION - HYPERFINE-INDEPENDENT VERSUS HYPERFINE-DEPENDENT MECHANISMS IN THE ST-MIXING OF ACETONE IN 2-PROPANOL

CHEMICAL PHYSICS LETTERS
  • M TERAZIMA
  • ,
  • Y MIURA
  • ,
  • K OHARA
  • ,
  • N HIROTA

224
1-2
開始ページ
95
終了ページ
100
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/0009-2614(94)00541-9
出版者・発行元
ELSEVIER SCIENCE BV

Chemically induced dynamic electron polarization (CIDEP) in an acetone/2-propanol system is investigated in the L band microwave frequency region at various temperatures. The polarization due to the ST- mechanism is analyzed in terms of the mixing of hyperfine-independent (ST-M-i) and hyperfine-dependent (ST-M-d) mechanisms. At higher temperature, ST-M-d dominates over ST-M-i in the ST-M polarization, while the relative contribution of ST-M-i increases with decreasing temperature. A mechanism of ST-M-d is discussed based on the radical diffusion in solution and a possible contribution of the ST+M polarization in the CIDEP spectrum is discussed.

リンク情報
DOI
https://doi.org/10.1016/0009-2614(94)00541-9
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:A1994NW29400017&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=2742595344&origin=inward
ID情報
  • DOI : 10.1016/0009-2614(94)00541-9
  • ISSN : 0009-2614
  • SCOPUS ID : 2742595344
  • Web of Science ID : WOS:A1994NW29400017

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