1994年7月
CIDEP MEASUREMENT IN THE L-BAND MICROWAVE FREQUENCY REGION - HYPERFINE-INDEPENDENT VERSUS HYPERFINE-DEPENDENT MECHANISMS IN THE ST-MIXING OF ACETONE IN 2-PROPANOL
CHEMICAL PHYSICS LETTERS
- ,
- ,
- ,
- 巻
- 224
- 号
- 1-2
- 開始ページ
- 95
- 終了ページ
- 100
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/0009-2614(94)00541-9
- 出版者・発行元
- ELSEVIER SCIENCE BV
Chemically induced dynamic electron polarization (CIDEP) in an acetone/2-propanol system is investigated in the L band microwave frequency region at various temperatures. The polarization due to the ST- mechanism is analyzed in terms of the mixing of hyperfine-independent (ST-M-i) and hyperfine-dependent (ST-M-d) mechanisms. At higher temperature, ST-M-d dominates over ST-M-i in the ST-M polarization, while the relative contribution of ST-M-i increases with decreasing temperature. A mechanism of ST-M-d is discussed based on the radical diffusion in solution and a possible contribution of the ST+M polarization in the CIDEP spectrum is discussed.
- リンク情報
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- DOI
- https://doi.org/10.1016/0009-2614(94)00541-9
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:A1994NW29400017&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=2742595344&origin=inward
- ID情報
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- DOI : 10.1016/0009-2614(94)00541-9
- ISSN : 0009-2614
- SCOPUS ID : 2742595344
- Web of Science ID : WOS:A1994NW29400017