論文

査読有り
2017年11月

Colloidal Synthesis of Air-Stable Alloyed CsSn1-xPxI3 Perovskite Nanocrystals for Use in Solar Cells

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • Feng Liu
  • Chao Ding
  • Yaohong Zhang
  • Teresa S. Ripolles
  • Taichi Kamisaka
  • Taro Toyoda
  • Shuzi Hayase
  • Takashi Minemoto
  • Kenji Yoshino
  • Songyuan Dai
  • Masatoshi Yanagida
  • Hidenori Noguchi
  • Qing Shen
  • 全て表示

139
46
開始ページ
16708
終了ページ
16719
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/jacs.7b08628
出版者・発行元
AMER CHEMICAL SOC

Organic-inorganic hybrid perovskite solar cells have demonstrated unprecedented high power conversion efficiencies in the past few years. Now, the universal instability of the perovskites has become the main barrier for this kind of solar cells to realize commercialization. This situation can be even worse for those tin-based perovskites, especially for CsSnI3, because upon exposure to ambient atmosphere the desired black orthorhombic phase CsSnI3 would promptly lose single crystallinity and degrade to the inactive yellow phase, followed by irreversible oxidation into metallic Cs2SnI6. By alloying CsSnI3 with CsPbI3, we herein report the synthesis of alloyed perovskite quantum dot (QD), CsSn1-xPbxI3, which not only can be phase-stable for months in purified colloidal solution but also remains intact even directly exposed to ambient air, far superior to both of its parent CsSnI3 and CsPbI3 QDs. Ultrafast transient absorption spectroscopy studies reveal that the photoexcited electrons in the alloyed QDs can be injected into TiO2 nanocrystals at a fast rate of 1.12 X 10(11) S-1 which enables a high photocurrent generation in solar cells.

リンク情報
DOI
https://doi.org/10.1021/jacs.7b08628
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000416496400043&DestApp=WOS_CPL
URL
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85034857310&origin=inward
ID情報
  • DOI : 10.1021/jacs.7b08628
  • ISSN : 0002-7863
  • eISSN : 1520-5126
  • Web of Science ID : WOS:000416496400043

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