2002年5月
Silicon-carbon unsaturated compounds. 65. Thermal and photochemical isomerization of trimethylsiloxy- and bis(trimethylsilyl)-substituted silacyclobut-3-enes
ORGANOMETALLICS
- ,
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- 巻
- 21
- 号
- 10
- 開始ページ
- 2033
- 終了ページ
- 2035
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1021/om020001v
- 出版者・発行元
- AMER CHEMICAL SOC
Heating silacyclobut-3-ene 2 at 250 degreesC afforded the trans-silacyclobut-3-ene 4, via the silyl-substituted cycloprop-2-ene 3. The photolysis of 4 gave a 1:1 mixture of 4 and the cis isomer 6, which was transformed into 4 at 250 degreesC, quantitatively. Preliminary results of the theoretical treatment for the isomerization of 2degrees to 3degrees are described.
- リンク情報
- ID情報
-
- DOI : 10.1021/om020001v
- ISSN : 0276-7333
- CiNii Articles ID : 80015285273
- Web of Science ID : WOS:000175632900005