MISC

2008年8月

Liquid-liquid phase equilibria of the system ethanol (1) plus water (2) plus tripotassium citrate (3)

JOURNAL OF CHEMICAL AND ENGINEERING DATA
  • Hirotake Katayama
  • ,
  • Kenta Sugahara

53
8
開始ページ
1940
終了ページ
1943
記述言語
英語
掲載種別
DOI
10.1021/je800092p
出版者・発行元
AMER CHEMICAL SOC

Liquid-liquid equilibria (LLE) for the system ethanol (1) + water (2) + tripotassium citrate (3) were measured at temperatures of (288.15, 298.15, and 308.15) K. The dependence of temperature on the LLE data is very small in the temperature range studied, but the slopes of the tie lines were found to decrease slightly with decreasing temperature. The binodal curves at each temperature were well fitted by a nonlinear equation with four parameters, and the tie line data were successfully correlated with the Othmer-Tobias and Bancroft equations. The LLE results were correlated using the nonlinear and Othmer-Tobias equations in addition to the nonlinear and Bancroft equations. Both correlations showed close agreement with experimental values, with (0.27 and 0.26) % as the average deviations of three temperatures, respectively.

リンク情報
DOI
https://doi.org/10.1021/je800092p
CiNii Articles
http://ci.nii.ac.jp/naid/80019764968
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000258503700043&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/je800092p
  • ISSN : 0021-9568
  • CiNii Articles ID : 80019764968
  • Web of Science ID : WOS:000258503700043

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