2000年6月
Electronic and vibrational spectra of aniline-benzene hetero-dimer and aniline homo-dimer ions
CHEMICAL PHYSICS LETTERS
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- 巻
- 323
- 号
- 1-2
- 開始ページ
- 43
- 終了ページ
- 48
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/S0009-2614(00)00497-8
- 出版者・発行元
- ELSEVIER SCIENCE BV
Structures of (aniline-benzene)(+) and (aniline)(2)(+) are re-investigated by electronic spectroscopy in the near-infrared region and vibrational spectroscopy in the NH stretching region. The spectra of (aniline-benzene)(+) indicate a structure including a hydrogen bond between an NH bond of the ionic aniline and the pi-electrons of the neutral benzene. Two isomers are suggested for (aniline)(2)(+) in which an NH bond of the ionic aniline forms different types of hydrogen bond with the neutral aniline: one with the pi-electrons of the aromatic ring and the other with the lone pair of the nitrogen atom. (C) 2000 Elsevier Science B.V. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/S0009-2614(00)00497-8
- ISSN : 0009-2614
- CiNii Articles ID : 80011766402
- Web of Science ID : WOS:000087538200007