1996年11月
Scavenging dynamics of photogenerated holes in poly(N-vinylcarbazole) films
JOURNAL OF PHYSICAL CHEMISTRY
- ,
- ,
- 巻
- 100
- 号
- 47
- 開始ページ
- 18436
- 終了ページ
- 18444
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- 出版者・発行元
- AMER CHEMICAL SOC
Diffusion-controlled scavenging of mobile holes under no applied electric field was observed directly in poly(N-vinylcarbazole) films, doped with 1,2,4,5-tetracyanobenzene (TCNB) as an electron acceptor and N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) as a hole scavenger, by transient absorption spectroscopy. The scavenging of holes occurs mainly over several nanoseconds, and is complete within 1 mu s. The mean diffusion length of the migrating holes was estimated to be similar to 15 Angstrom. A Monte Carlo simulation of 3-D diffusion in energetically disordered media was applied for analyzing the hole-scavenging behavior. The spatially restricted character of the hole migration was revealed by the simulation. A very slow (up to several tens of milliseconds) recombination of TMPD cations with TCNB anions was also observed, which was explained in terms of a long-range electron tunneling.
- リンク情報
- ID情報
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- ISSN : 0022-3654
- Web of Science ID : WOS:A1996VU82500022