MISC

1999年7月

Infrared spectra of Dewar 2-picoline in low-temperature argon matrices

CHEMICAL PHYSICS LETTERS
  • S Kudoh
  • ,
  • M Takayanagi
  • ,
  • M Nakata

308
5-6
開始ページ
403
終了ページ
407
記述言語
英語
掲載種別
DOI
10.1016/S0009-2614(99)00624-7
出版者・発行元
ELSEVIER SCIENCE BV

Infrared spectra of Dewar 2-picoline, produced from 2-picoline in an argon matrix by UV irradiation, were measured. The observed bands were assigned to a single isomer, which has a C-C bridging bond and an N=C-CH3 group, with the aid of DFT calculations, where the 6-31 + + G * * basis set was used to optimize the geometrical structure. No other isomer bands were observed. The selectivity of the isomerization to Dewar 2-picoline is discussed in terms of the atomic charge distribution in electronically excited states of 2-picoline. (C) 1999 Elsevier Science B.V. All rights reserved.

Web of Science ® 被引用回数 : 7

リンク情報
DOI
https://doi.org/10.1016/S0009-2614(99)00624-7
CiNii Articles
http://ci.nii.ac.jp/naid/80011262347
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000081731600009&DestApp=WOS_CPL