2013年
Simplified Model for Extraction of 5-Hydroxymethylfurfural from Fructose: Use of Water/Oil Biphasic System under High Temperature and Pressure Conditions
SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN
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- 巻
- 20
- 号
- 開始ページ
- 205
- 終了ページ
- 212
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.15261/serdj.20.205
- 出版者・発行元
- JAPAN ASSOC SOLVENT EXTRACTION
5-Hydroxymethylfurfural (HMF) was obtained from the dehydration of fructose under high temperature and pressure conditions (180 degrees C and 10 MPa). To avoid the decomposition of HMF in the bulk aqueous phase, we dehydrated fructose in the water / metyl isobuthyl ketone (MIBK) biphasic system. The HMF could be successfully extracted into the organic MIBK phase without further decomposition of HMF. We present a simplified model taking into consideration of the slug flow with the wall film to maximize the HMF yield in the MIBK phase. It was likely that the slug flow contributed to an increase in the surface-to-volume ratio for the mass transfer of HMF.
- リンク情報
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- DOI
- https://doi.org/10.15261/serdj.20.205
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000322290600021&DestApp=WOS_CPL
- URL
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84879226936&origin=inward
- ID情報
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- DOI : 10.15261/serdj.20.205
- ISSN : 1341-7215
- SCOPUS ID : 84879226936
- Web of Science ID : WOS:000322290600021