論文

国際誌
2021年6月22日

Decoupling between calorimetric and dynamical glass transitions in high-entropy metallic glasses.

Nature communications
  • Jing Jiang
  • ,
  • Zhen Lu
  • ,
  • Jie Shen
  • ,
  • Takeshi Wada
  • ,
  • Hidemi Kato
  • ,
  • Mingwei Chen

12
1
開始ページ
3843
終了ページ
3843
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1038/s41467-021-24093-w

Glass transition is one of the unresolved critical issues in solid-state physics and materials science, during which a viscous liquid is frozen into a solid or structurally arrested state. On account of the uniform arrested mechanism, the calorimetric glass transition temperature (Tg) always follows the same trend as the dynamical glass transition (or α-relaxation) temperature (Tα) determined by dynamic mechanical analysis (DMA). Here, we explored the correlations between the calorimetric and dynamical glass transitions of three prototypical high-entropy metallic glasses (HEMGs) systems. We found that the HEMGs present a depressed dynamical glass transition phenomenon, i.e., HEMGs with moderate calorimetric Tg represent the highest Tα and the maximum activation energy of α-relaxation. These decoupled glass transitions from thermal and mechanical measurements reveal the effect of high configurational entropy on the structure and dynamics of supercooled liquids and metallic glasses, which are associated with sluggish diffusion and decreased dynamic and spatial heterogeneities from high mixing entropy. The results have important implications in understanding the entropy effect on the structure and properties of metallic glasses for designing new materials with plenteous physical and mechanical performances.

リンク情報
DOI
https://doi.org/10.1038/s41467-021-24093-w
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/34158476
PubMed Central
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8219663
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85108323711&origin=inward 本文へのリンクあり
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85108323711&origin=inward
ID情報
  • DOI : 10.1038/s41467-021-24093-w
  • eISSN : 2041-1723
  • PubMed ID : 34158476
  • PubMed Central 記事ID : PMC8219663
  • SCOPUS ID : 85108323711

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