論文

2001年1月

Multielement determination of trace elements in seawater by inductively coupled plasma mass spectrometry after tandem preconcentration with cooperation of chelating resin adsorption and lanthanum coprecipitation

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
  • T Yabutani
  • ,
  • K Chiba
  • ,
  • H Haraguchi

74
1
開始ページ
31
終了ページ
38
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1246/bcsj.74.31
出版者・発行元
CHEMICAL SOC JAPAN

A tandem preconcentration method, in which chelating resin adsorption and La coprecipitation were cooperatively employed for preconcentration, was developed as a pretreatment method for simultaneous multielement determination of trace elements in seawater by ICP-MS. First, the seawater sample (250 ml) was treated with a chelating resin for preconcentration of trace elements, and then trace elements with good recoveries were determined by ICP-MS. Trace elements with the chemical properties of oxoanion- and hydride-formation, which were poorly recovered in the chelating resin preconcentration, were further subjected to preconcentration by La coprecipitation. As a result, more than 30 elements could be determined in the concentration range from 9.6 mug L-1 for Mo to 0.00018 mug L-1 for Tm, when the present tandem method was applied to the analysis of open seawater standard reference material (NASS-4). Furthermore, the analytical results for open seawater reference materials were compared with those for coastal seawater reference material as well as for coastal seawater collected in the Ise Bay. It was found that the multielement data for trace elements in these seawater samples clearly showed different elemental distributions, reflecting the different marine environments.

リンク情報
DOI
https://doi.org/10.1246/bcsj.74.31
CiNii Articles
http://ci.nii.ac.jp/naid/10009157186
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000167288000003&DestApp=WOS_CPL
ID情報
  • DOI : 10.1246/bcsj.74.31
  • ISSN : 0009-2673
  • eISSN : 1348-0634
  • CiNii Articles ID : 10009157186
  • identifiers.cinii_nr_id : 9000000402644
  • Web of Science ID : WOS:000167288000003

エクスポート
BibTeX RIS