論文

2008年2月

Kinetics of the reaction of TiO X-3 Delta with O-2, H-2, N-2, CH4, C2H6, and C2H4

CHEMICAL PHYSICS LETTERS
  • Yoko Higuchi
  • ,
  • Yuko Fukuda
  • ,
  • Yukiko Fujita
  • ,
  • Nami Yamakita
  • ,
  • Takashi Imajo

452
4-6
開始ページ
245
終了ページ
248
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.cplett.2007.12.067
出版者・発行元
ELSEVIER SCIENCE BV

We report the kinetics of the gas-phase reactions of TiO X-3 Delta with O-2, H-2, N-2, CH4, C2H4, and C2H6 at 297 K and total pressures of up to 2.00 Torr using an argon bath gas. TiO was produced by the reaction of Ti atoms generated by laser vaporization with 02 and was detected using cavity ring-down spectroscopy. No reaction was observed with H-2, N-2, CH4, and C2H6. The rate constant with C2H4 was found to depend on the total pressure, suggesting a reaction mechanism involving an adduct formation. (c) 2008 Elsevier B.V. All rights reserved.

Web of Science ® 被引用回数 : 2

リンク情報
DOI
https://doi.org/10.1016/j.cplett.2007.12.067
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000253767100003&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.cplett.2007.12.067
  • ISSN : 0009-2614
  • Web of Science ID : WOS:000253767100003

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