1997年1月
Fluorescence line narrowing spectroscopy of Sm2+ and Eu3+ in sodium borate glasses
JOURNAL OF APPLIED PHYSICS
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- ,
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- 巻
- 81
- 号
- 2
- 開始ページ
- 924
- 終了ページ
- 930
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1063/1.364223
- 出版者・発行元
- AMER INST PHYSICS
A fluorescence Line narrowing technique was carried out for sodium borate glasses containing a Sm2+ ion and its isoelectonic Eu3+ ion under a pulsed tunable dye laser excitation. In order to obtain site-dependent information, measurements were made by exciting the inhomogeneously broadened D-5(0)-F-7(0) transition at 10 K. Line-narrowing fluorescence of the D-5(0)-->F-7(1) transition and the temporal changes of the emission lines were investigated as a function of excitation energy, and the dynamics of excited states for both ions were compared with each other, The results indicate that the site-to-site variations of the inhomogeneous broadening of D-5(0)-F-7(0) transitions are attributed to the apparent difference in local environment between the Sm2+ and Eu3+ ions doped in borate glasses with Na2O content from 10 to 20 mol %. Also, a decrease in concentration of rare-earth ions causes a more significant effect on Eu3+ ions than on Sm2+ ions in the ki,oh-excitation-energy range. It is concluded that the difference in the local environment between Sm2+ and Eu3+ is mainly ascribable to the difference in the valence and in the ionic radius. (C) 1997 American Institute of Physics.
- リンク情報
- ID情報
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- DOI : 10.1063/1.364223
- ISSN : 0021-8979
- Web of Science ID : WOS:A1997WD71600056