2013年
Helix-sense-selective polymerization of substituted acetylenes by using an isolated rh chiral initiator with an amino acid ligand
Chemistry Letters
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- ,
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- 巻
- 42
- 号
- 4
- 開始ページ
- 430
- 終了ページ
- 432
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.121295
Helix-sense-selective polymerization (HSSP) of substituted acetylenes by using an isolated chiral Rh initiator with an amino acid ligand has been achieved. The sense of the helix of the main chain of the resulting polymer was controlled by the sign of the chirality of the ligand. The isolated initiator needed less of the chiral ligand and gave polymers having a higher value than the two component chiral initiator systems we reported previously. The resulting polymers had a higher Mw. © 2013 The Chemical Society of Japan.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.121295
- ISSN : 0366-7022
- ISSN : 1348-0715
- SCOPUS ID : 84875978672