2015年12月
Highly Efficient Helix-sense-selective Polymerization of an Achiral Phenylacetylene Having a Bulky Group
CHEMISTRY LETTERS
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- 巻
- 44
- 号
- 12
- 開始ページ
- 1777
- 終了ページ
- 1779
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.150863
- 出版者・発行元
- CHEMICAL SOC JAPAN
A novel achiral phenylacetylene having a bulky t-butyl group was synthesized and polymerized by a chiral catalytic system containing [Rh(nbd)Cl](2) (nbd: norbomadiene) and chiral amines to yield a one-handed helical polymer having a much higher g value than polymers with no bulky groups. Highly efficient helix-sense-selective polymerization has been achieved using a bulky monomer and a less bulky chiral cocatalyst.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.150863
- ISSN : 0366-7022
- eISSN : 1348-0715
- Web of Science ID : WOS:000365933300049