論文

査読有り
2015年9月

Exciton Diffusion in Conjugated Polymers: From Fundamental Understanding to Improvement in Photovoltaic Conversion Efficiency

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
  • Yasunari Tamai
  • ,
  • Hideo Ohkita
  • ,
  • Hiroaki Benten
  • ,
  • Shinzaburo Ito

6
17
開始ページ
3417
終了ページ
3428
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/acs.jpclett.5b01147
出版者・発行元
AMER CHEMICAL SOC

Singlet exciton diffusion plays a central role in the photovoltaic conversion in organic photovoltaics (OPVs). Upon light absorption, singlet excitons are promptly generated in organic materials instead of charge carriers because the dielectric constant (epsilon(r)) is small (similar to 3-4), which is in sharp contrast to inorganic and perovskite solar cells. In order to convert to charge carriers, excitons need to diffuse into an interface between electron donor and acceptor materials before deactivating to the ground state. Therefore, fundamental understanding of exciton diffusion dynamics is one of the most important issues to further improve OPVs. We highlight recent leading studies in this field and describe several approaches for efficient exciton harvesting at the interface in OPVs.

リンク情報
DOI
https://doi.org/10.1021/acs.jpclett.5b01147
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000360953300017&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/acs.jpclett.5b01147
  • ISSN : 1948-7185
  • Web of Science ID : WOS:000360953300017

エクスポート
BibTeX RIS