2014年4月
Triplet Exciton Dynamics in Fluorene-Amine Copolymer Films
CHEMISTRY OF MATERIALS
- ,
- ,
- ,
- 巻
- 26
- 号
- 8
- 開始ページ
- 2733
- 終了ページ
- 2742
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/cm500647b
- 出版者・発行元
- AMER CHEMICAL SOC
Effect of aromaticity on triplet exciton dynamics was studied by transient absorption spectroscopy for two fluorene-based random copolymers with different aromatic amine, poly(9,9'-di-n-octylfluorene-ran-N,N'-bis(4-n-butylphenyl)-N,N'-diphenyl-1,4-benzenediamine) (F8-PDA) and poly(9,9'-di-n-octylfluorene-ran-N,N'-bis(4-t-butylphenyl)-N,N'-di- pheny1-9,10-anthracenediamine) (F8-ADA). On a time scale of nanoseconds, triplet exciton was efficiently formed in F8-PDA through the intersystem crossing (ISC) from singlet exciton with a rate constant of 2.0 X 10(8) s(-1). On the other hand, the ISC was not efficient in F8-ADA, resulting in efficient fluorescence emission. On a time scale of micro- to milliseconds, F8-PDA exhibited bimolecular triplet exciton decay due to triplet-triplet annihilation (TTA), but the TTA was negligible in F8-ADA, indicating that triplet excitons can diffuse freely in F8-PDA while they are trapped at ADA units in F8-ADA. The difference in the ISC efficiency and triplet exciton diffusion is discussed in terms of the aromaticity of the amine units. On the basis of these analyses, we discuss a strategy for further improvement in the efficiency of fluorene-amine copolymer based light-emitting diodes.
- リンク情報
- ID情報
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- DOI : 10.1021/cm500647b
- ISSN : 0897-4756
- eISSN : 1520-5002
- Web of Science ID : WOS:000334991300033