2010年
Solution-processed multilayered polymer solar cells designed by layer-by-layer assembly of poly(p-phenylenevinylene)s with dimethylsulfoxide
TRANSACTIONS OF MATERIALS RESEARCH SOCIETY OF JAPAN
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- 巻
- 35
- 号
- 1
- 開始ページ
- 31
- 終了ページ
- 34
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.14723/tmrsj.35.31
- 出版者・発行元
- The Materials Research Society of Japan
Multilayered polymer solar cells were fabricated by a combination of spin-coating and layer-by-layer (LbL) deposition techniques. A light-harvesting layer was precisely designed by LbL assembly of poly(p-phenylenevinylene) (PPV) and an anionic PPV derivative, poly[5-methoxy-2-(3-sulfopropoxy)-1,4-phenylenevinylene] (MPS-PPV). The remaining hole-transporting and electron-transporting layers were prepared by the spin-coating method. In order to improve optical properties of the MPS-PPV LbL film, dimethylsulfoxide (DMSO) was added to an aqueous solution of MPS-PPV. As a result, the absorption of PPV/MPS-PPV LbL films increased at around 500 nm compared with that of the reference LbL films fabricated from an aqueous solution of MPS-PPV. The short-circuit current density of the multilayered polymer solar cell was improved by > 10% compared to the reference cell with PPV/MPS-PPV LbL layers fabricated from the aqueous solution. Furthermore, the external quantum efficiency at around 500 nm was also improved, suggesting the increase in the light-harvesting efficiency of the LbL layer fabricated from the water/DMSO mixed solution of MPS-PPV.
- リンク情報
- ID情報
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- DOI : 10.14723/tmrsj.35.31
- ISSN : 1382-3469
- CiNii Articles ID : 130003398888