論文

査読有り
2001年

Theoretical approach to the design of supramolecular conjugated porphyrin polymers

JOURNAL OF MATERIALS CHEMISTRY
  • K Susumu
  • ,
  • H Maruyama
  • ,
  • H Kobayashi
  • ,
  • K Tanaka

11
9
開始ページ
2262
終了ページ
2270
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/b102614n
出版者・発行元
ROYAL SOC CHEMISTRY

The design of novel conjugated polymers mainly consisting of porphyrin and/or phthalocyanine rings is Studied by the use of the tight-binding crystal orbital method based on the extended Huckel approximation. This paper focuses on the tuning of the electronic structures of these polymers by ethynyl bridging as well as various linkage modes. It has been clarified that the bridging sites (meso-to-meso, meso-to-beta and beta -to-beta) and the bridging patterns (linear or zigzag) in the ethynyl-bridged porphyrin polymers are crucial for tuning the pi -conjugation throughout the main chain. Furthermore, comparison of two-dimensional (2D) porphyrin polymer sheets and stacked porphyrin polymers demonstrates quite different electronic properties.

リンク情報
DOI
https://doi.org/10.1039/b102614n
J-GLOBAL
https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902137882150701
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000171023000030&DestApp=WOS_CPL
ID情報
  • DOI : 10.1039/b102614n
  • ISSN : 0959-9428
  • J-Global ID : 200902137882150701
  • Web of Science ID : WOS:000171023000030

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