2003年12月
Novel synthesis of azocine, azepine, oxocine, and oxepine derivatives by palladium-catalyzed medium-ring formation from bromoallenes
HETEROCYCLES
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- 巻
- 61
- 号
- 開始ページ
- 65
- 終了ページ
- +
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
Novel and efficient synthesis of medium-sized heterocycles such as azepine, oxepine, and benzo[d]azocine derivatives is described. Treatment of bromoallenes having a nucleophilic moiety with sodium alkoxide and a palladium(0) catalyst in the presence of an alcohol leads to regioselective formation of medium-sized rings at the central position of the allenic carbon.
- リンク情報
- ID情報
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- ISSN : 0385-5414
- CiNii Articles ID : 80016354250
- Web of Science ID : WOS:000188053700014