2003年12月
Novel synthesis of 3-azabicyclo[3.1.0]hexanes by unusual palladium(0)-catalyzed cyclopropanation of allenenes
ORGANIC LETTERS
- ,
- ,
- ,
- ,
- 巻
- 5
- 号
- 25
- 開始ページ
- 4763
- 終了ページ
- 4766
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1021/ol0356441
- 出版者・発行元
- AMER CHEMICAL SOC
[GRAPHICS]
Novel stereoselective synthesis of 3-azabicyclo[3.1.0]hexanes from allenenes is presented. Treatment of N-protected 4-alkyl-4-(N-allyl)amino allenes with allyl carbonate and a catalytic amount of Pd-2(dba)(3).CHCl3 in MeCN leads to stereoselective formation of the 3-azabicyclo[3.1.0]-hexane framework in moderate to good yields.
Novel stereoselective synthesis of 3-azabicyclo[3.1.0]hexanes from allenenes is presented. Treatment of N-protected 4-alkyl-4-(N-allyl)amino allenes with allyl carbonate and a catalytic amount of Pd-2(dba)(3).CHCl3 in MeCN leads to stereoselective formation of the 3-azabicyclo[3.1.0]-hexane framework in moderate to good yields.
- リンク情報
- ID情報
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- DOI : 10.1021/ol0356441
- ISSN : 1523-7060
- PubMed ID : 14653668
- Web of Science ID : WOS:000187038300003