2012年6月
Gold(I)-Catalyzed Regioselective Inter-/Intramolecular Addition Cascade of Di- and Triynes for Direct Construction of Substituted Naphthalenes
JOURNAL OF ORGANIC CHEMISTRY
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- 巻
- 77
- 号
- 11
- 開始ページ
- 4907
- 終了ページ
- 4916
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/jo300771f
- 出版者・発行元
- AMER CHEMICAL SOC
The gold-catalyzed cascade intermolecular addition-intramolecular carbocyclization reaction of diallcynylbenzenes was developed. In this reaction, regioselective addition of an external nucleophile toward the terminal alkyne and subsequent 6-endo-dig cyclization proceeded to give the 1,3-disubstituted naphthalenes in good yields. The direct synthesis of disubstituted chrysenes via a gold-catalyzed addition and double cyclization cascade using a triyne-type substrate was also achieved.
- リンク情報
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- DOI
- https://doi.org/10.1021/jo300771f
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201202233603415878
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/22568806
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000304682400004&DestApp=WOS_CPL
- ID情報
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- DOI : 10.1021/jo300771f
- ISSN : 0022-3263
- J-Global ID : 201202233603415878
- PubMed ID : 22568806
- Web of Science ID : WOS:000304682400004