2013年2月
Analysis of Low-Lying Gerade Rydberg States of Acetylene Using Two-Photon Resonance Fluorescence Excitation Spectroscopy
JOURNAL OF PHYSICAL CHEMISTRY A
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- 巻
- 117
- 号
- 7
- 開始ページ
- 1420
- 終了ページ
- 1427
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/jp308406r
- 出版者・発行元
- AMER CHEMICAL SOC
The np gerade Rydberg states of acetylene were analyzed using two-photon resonance fluorescence excitation spectroscopy in the 72 000-93 000 cm(-1) energy region. The np pi(1)Sigma(+)(8); and np pi(1)triangle(g) Rydberg series (n = 3-5) were identified in the fluorescence excitation spectrum measured by monitoring the C-2 d(3)Pi(8)-a(3)Pi(u) Swan system. Some vibronic bands were assigned to the np pi(1)Delta(g)-X-1 Sigma(+)(8); transition on the basis of rotational analysis. The 5p sigma(1)Pi(g) state was observed, which is the first such observation in an np sigma(1)Pi(g) series. Rotational analysis of the 5p sigma(1)Pi(g)-X-1 Sigma(+)(g) transition showed e/f-symmetry dependent predissociation of acetylene in the 5p sigma(1)Pi(g) state. The 0(0)(0) band of the deuterated acetylene (C2D2) 4p pi(1)Sigma(+)(g) - X-1 Sigma(+)(g) transition exhibits an atypical structure, which was satisfactorily reproduced by a simple model of quantum interference between the discrete and quasi-continuum states. The predissociative lifetimes of the np pi gerade Rydberg states were estimated from the spectral profiles. The predissociation mechanism of acetylene in the Rydberg states is discussed.
- リンク情報
- ID情報
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- DOI : 10.1021/jp308406r
- ISSN : 1089-5639
- J-Global ID : 201302282993895830
- Web of Science ID : WOS:000315432300006