SASAMORI Takahiro

Last updated: Mar 30, 2019 at 07:50

Name	SASAMORI Takahiro
URL	http://www.nsc.nagoya-cu.ac.jp/~sasamori/www/index.html
Affiliation	Nagoya City University
Section	Graduate School of Natural Sciences　Division of Mathematical and Material Science
Job title	Professor
Degree	Doctor of Science(Kyushu University)

Profile

2017(April)- present

Full Professor at Graduate School of Natural Sciences, NAGOYA CITY UNIVERSITY
2009(July)- 2017(March)

Associate Professor at Institute for Chemical Research, KYOTO UNIVERSITY (Prof. Norihiro Tokitoh’s group)
2003(April)-2009(June)

Assistant Professor at Institute for Chemical Research, KYOTO UNIVERSITY (Prof. Norihiro Tokitoh’s group)
2002(April)-2003(March)

Postdoctoral Fellow at Institute for Chemical Research, KYOTO UNIVERSITY (Prof. Norihiro Tokitoh’s group)
1999(April)-2002(March)

Ph.D. course at Graduate School of Science/ KYUSHU UNIVERSITY with Thesis entitled “Studies on the Synthesis of Low-coordinated Species of Heavier Group 15 Elements Utilizing Kinetic Stabilization and Their Properties”
Supervisors; Prof. Mizue Fujio and Prof. Norihiro Tokitoh.
1997(April)-1999(March)

M. Sc. course at Graduate School of Science/THE UNIVERSITY OF TOKYO with Thesis entitled “Synthesis of Low-coordinated Organoantimony and Organobismuth Compounds by Taking Advantage of Steric Protection and Their Properties”
Supervisor; Prof. Takayuki Kawashima.
1996(April)-1997(March)

B.Sc. course at Graduate School of Science/THE UNIVERSITY OF TOKYO
Supervisor; Prof. Renji Okazaki.

Research Interests

Organoelement Chemistry(5)

Research Areas

Chemistry / Organic chemistry /

Academic & Professional Experience

Plain Text

Apr 2017

Today

Professor, Graduate School of Natural Sciences, Nagoya City University

Jul 2009

Mar 2017

Asssociate Professor, Organoelement Cheimstry Division, Institute for Chemical Research

Apr 2006

Jun 2009

Assistant Professor, Organoelement Cheimstry Division, Institute for Chemical Research

Apr 2003

Mar 2006

Assistant Professor, Organoelement Cheimstry Division, Institute for Chemical Research

1999

2002

Research Fellowship for Young Scientists

2002

2003

Postdoctoral Fellow at Institute for Chemical Research, Kyoto University (Prof. Norihiro Tokitoh’s group)

2003

Assistant Prof. at Institute for Chemical Research, Kyoto University (Prof. Norihiro Tokitoh’s group)

Education

Plain Text

1999

Graduate School, Division of Science, The University of Tokyo

1997

Faculty of Science, The University of Tokyo

Awards & Honors

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Nov 2016

Reaction of a Stable Digermyne with Acetylenes: Synthesis of a 1,2-Digermabenzene and a 1,4-Digermabarrelene, BCSJ Award, BCSJ

Winner: T. Sugahara, J.-D. Guo, T. Sasamori, Y. Karatsu, Y. Furukawa, A. E. Ferao, S. Nagase, N. Tokitoh

May 2014

The Friedrich Wilhelm Bessel Research Award, Alexander von Humboldt Foundation

Oct 2013

1,2-Bis(ferrocenyl)dipnictenes: Bimetallic Systems with a Pn=Pn Heavy π-spacer (Pn: P, Sb, and Bi), BCSJ Award, BCSJ

Winner: M. Sakagami, T. Sasamori, H. Sakai, Y. Furukawa, N. Tokitoh

Feb 2012

Creation of Novel Main Group Element Photo-catalysts utilizing Control of Coordination Numbers, Sumitomo Chemical Co., Ltd. Award in Synthetic Organic Chemistry, Japan,, The Society of Synthetic Organic Chemistry JAPAN

Apr 2011

Research on π-Electron Systems of Heavier Main Group Elements in Pursuit of Functions, the Young Scientists' Prize, Minister of Education, Culture, Sports, Science and Technology, Japan

May 2010

Synthesis, Structures, and Reactivity of Kinetically Stabilized Anthryldiphosphene Derivatives, BCSJ Award, BCSJ

Winner: A. Tsurusaki, N. Nagahora, T. Sasamori, K. Matsuda, Y. Kanemitsu, Y. Watanabe, Y. Hosoi, Y. Furukawa, N. Tokitoh

Mar 2010

Creation of π-Electron Systems of Heavier Main Group Elements in Pursuit of Functions, Chemical Society of Japan Award for Young Chemists, Chemical Society of Japan

Oct 2009

Creation of π-Electron Systems of Heavier Group 14 Elements in Pursuit of Functions, Progress Award in Silicon Chemistry, The Society of Silicon Chemistry JAPAN

Jul 2009

1,2-Bis(metallocenyl)disilenes: Novel d-π Conjugated Systems with an Si=Si Double Bond, BCSJ Award, BCSJ

Winner: A. Yuasa, T. Sasamori, Y. Hosoi, Y. Furukawa, N. Tokitoh

Oct 2007

Kinetically Stabilized 1,1′-Bis[(E)-diphosphenyl]ferrocenes: Syntheses, Structures, Properties, and Reactivity, BCSJ Award, BCSJ

Winner: N. Nagahora, T. Sasamori, Y. watanabe, Y. Furukawa, N. Tokitoh

Feb 2007

Creation of Novel Organic Materials utilizing π-Electron Systems of Heavier Main Group Elements, Daiichi Pharmaceutical Co., Ltd. Award in Synthetic Organic Chemistry, Japan,, The Society of Synthetic Organic Chemistry JAPAN

Winner: Takahiro Sasamori

Dec 2006

Double Bond Compounds between Heavier Group 15 Elements, The ICR Award for Young Scientists, Institute for Chemical Research, Kyoto University

Winner: Takahiro Sasamori

Jun 2005

Synthesis of Kinetically Stabilized 1-Silanaphthalenes and Their Properties, BCSJ Award, BCSJ

Winner: A. Shinohara, N. Takeda, T. Sasamori, N. Tokitoh

Feb 2005

Studies on the Synthesis of Low-coordinated Species of Heavier Group 15 Elements Utilizing Kinetic Stabilization and Their Properties, Inoue Research Award for Young Scientist, Inoue Foundation for Science

Winner: Takahiro Sasamori

Sep 2002

Synthesis, Structures, and Properties of Kinetically Stabilized Distibenes and Dibismuthenes, Novel Doubly Bonded Systems between Heavier Group 15 Elements, BCSJ Award, BCSJ

Winner: T. Sasamori, Y. Arai, N. Takeda, R. Okazaki, Y. Furukawa, M. Kimura, S. Nagase, N. Tokitoh

2002

The BCSJ Award (The Best Article of the Month)

2005

The BCSJ Award (The Best Article of the Month)

2007

The BCSJ Award (The Best Article of the Month)

Published Papers

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Structure-efficiency relationship of photoinduced electron transfer-triggered nitric oxide releasers.

Ieda N, Oka Y, Yoshihara T, Tobita S, Sasamori T, Kawaguchi M, Nakagawa H

Scientific reports 9(1) 1430 Feb 2019 [Refereed]

Reversible Isomerizations between 1,4-Digermabenzenes and 1,4-Digerma-Dewar-benzenes: Air-Stable Activators for Small Molecules.

Sugahara T, Guo JD, Hashizume D, Sasamori T, Tokitoh N

Journal of the American Chemical Society 141(6) 2263-2267 Feb 2019 [Refereed]

Activation of Small Molecules by Compounds that Contain Triple Bonds Between Heavier Group-14 Elements.

Guo JD, Sasamori T

Chemistry, an Asian journal 13(24) 3800-3817 Dec 2018 [Refereed]

2,5-Digermaselenophenes: Germanium Analogues of Selenophenes.

Sugahara T, Sasamori T, Tokitoh N

Journal of the American Chemical Society 140(36) 11206-11209 Sep 2018 [Refereed]

The selective formation of a 1,2-disilabenzene from the reaction of a disilyne with phenylacetylene.

Sugahara T, Guo JD, Hashizume D, Sasamori T, Nagase S, Tokitoh N

Dalton transactions (Cambridge, England : 2003) 47(38) 13318-13322 Aug 2018 [Refereed]

Tetrylones: An Intriguing Class of Monoatomic Zero-valent Group14 Compounds

Majhi Paresh Kumar, Sasamori Takahiro

CHEMISTRY-A EUROPEAN JOURNAL 24(38) 9441-9455 Jul 2018 [Refereed]

Synthesis of Ferrocenyl-Substituted Organochalcogenyldichlorogermanes

Inorganics Jul 2018 [Refereed]

Chalcogenation Reaction of Cyclic Digermenes

Sugahara Tomohiro, Sasamori Takahiro, Tokitoh Norihiro

CHEMISTRY LETTERS 47(6) 719-722 Jun 2018 [Refereed]

Synthesis and Structure of Lewis Base-Coordinated Phosphanylalumanes Bearing P-H and Al-Br Moieties

Agou Tomohiro, Ikeda Shin, Sasamori Takahiro, Tokitoh Norihiro

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (19) 1984-1987 May 2018 [Refereed]

Synthesis and Structure of a Stable Bis(methylene)-lambda(4)-sulfane

Sugamata Koh, Hashizume Daisuke, Suzuki Yuko, Sasamori Takahiro, Ishii Shigeru

CHEMISTRY-A EUROPEAN JOURNAL 24(27) 6922-6926 May 2018 [Refereed]

Sigmatropic Rearrangements of Hypervalent-Iodine-Tethered Intermediates for the Synthesis of Biaryls

Hori Mitsuki, Guo Jing-Dong, Yanagi Tomoyuki, Nogi Keisuke, Sasamori Takahiro, Yorimitsu Hideki

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57(17) 4663-4667 Apr 2018 [Refereed]

Regioselective Cyclotrimerization of Terminal Alkynes Using a Digermyne

Sugahara Tomohiro, Guo Jing-Dong, Sasamori Takahiro, Nagase Shigeru, Tokitoh Norihiro

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57(13) 3499-3503 Mar 2018 [Refereed]

Intermolecular chemo- and regioselective aromatic C-H amination of alkoxyarenes promoted by rhodium nitrenoids

Arai Kenta, Ueda Yoshihiro, Morisaki Kazuhiro, Furuta Takumi, Sasamori Takahiro, Tokitoh Norihiro, Kawabata Takeo

CHEMICAL COMMUNICATIONS 54(18) 2264-2267 Mar 2018 [Refereed]

Synthesis and Characterization of N-Heterocyclic Carbene-Coordinated Silicon Compounds Bearing a Fused-Ring Bulky Eind Group

Hayakawa Naoki, Sadamori Kazuya, Mizutani Shinsuke, Agou Tomohiro, Sugahara Tomohiro, Sasamori Takahiro, Tokitoh Norihiro, Hashizume Daisuke, Matsuo Tsukasa

INORGANICS 6(1) Mar 2018 [Refereed]

1,2-Dihalodigermenes bearing bulky Eind groups: synthesis, characterization, and conversion to halogermylenoids

Hayakawa Naoki, Sugahara Tomohiro, Numata Yasuyuki, Kawaai Hotaka, Yamatani Kenta, Nishimura Shogo, Goda Shun, Suzuki Yuko, Tanikawa Tomoharu, Nakai Hidetaka, Hashizume Daisuke, Sasamori Takahiro, Tokitoh Norihiro, Matsuo Tsukasa

DALTON TRANSACTIONS 47(3) 814-822 Jan 2018 [Refereed]

Reversible addition of terminal alkenes to digermynes

Sugahara Tomohiro, Guo Jing-Dong, Sasamori Takahiro, Nagase Shigeru, Tokitoh Norihiro

CHEMICAL COMMUNICATIONS 54(5) 519-522 Jan 2018 [Refereed]

A Redox-Active Bis(ferrocenyl)germylene and Its Reactivity

Suzuki Yuko, Sasamori Takahiro, Guo Jing-Dong, Tokitoh Norihiro

CHEMISTRY-A EUROPEAN JOURNAL 24(2) 364-368 Jan 2018 [Refereed]

Synthesis and Structural Properties of Axially Chiral Binaphthothiophene Dicarboxylic Acid.

Murai T, Xing Y, Kuribayashi T, Lu W, Guo JD, Yella R, Hamada S, Sasamori T, Tokitoh N, Kawabata T, Furuta T

Chemical & pharmaceutical bulletin 66(12) 1203-1206 2018 [Refereed]

Synthesis of a Dichlorodigermasilane: Double Si-Cl Activation by a Ge=Ge Unit

Sugahara Tomohiro, Tokitoh Norihiro, Sasamori Takahiro

INORGANICS 5(4) Dec 2017 [Refereed]

Formation of Phenalenone Skeleton by an Unusual Rearrangement Reaction

Sasaki Sayaka, Azuma Eriko, Sasamori Takahiro, Tokitoh Norihiro, Kuramochi Kouji, Tsubaki Kazunori

ORGANIC LETTERS 19(18) 4846-4849 Sep 2017 [Refereed]

Highly Bent 1,3-Digerma-2-silaallene

Sugahara Tomohiro, Sasamori Takahiro, Tokitoh Norihiro

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56(33) 9920-9923 Aug 2017 [Refereed]

Effects of counter anions, P-substituents, and solvents on optical and photophysical properties of 2-phenylbenzo[b]phospholium salts

Koyanagi Yoshinari, Kawaguchi Shogo, Fujii Kaori, Kimura Yoshifumi, Sasamori Takahiro, Tokitoh Norihiro, Matano Yoshihiro

DALTON TRANSACTIONS 46(29) 9517-9527 Aug 2017 [Refereed]

Synthesis and Structures of Zigzag Shaped [12]Cyclo-p-phenylene Composed of Dinaphthofuran Units and Biphenyl Units

Shouda Takaaki, Nakanishi Kentaro, Sasamori Takahiro, Tokitoh Norihiro, Kuramochi Kouji, Tsubaki Kazunori

JOURNAL OF ORGANIC CHEMISTRY 82(15) 7850-7855 Aug 2017 [Refereed]

1,4-Diphosphinines from Imidazole-2-thiones

Koner Abhishek, Pfeifer Gregor, Kelemen Zsolt, Schnakenburg Gregor, Nyulaszi Laszlo, Sasamori Takahiro, Streubel Rainer

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56(31) 9231-9235 Jul 2017 [Refereed]

Inorganic-Salt-Free Reduction in Main-Group Chemistry: Synthesis of a Dibismuthene and a Distibene

Majhi Paresh Kumar, Ikeda Hideaki, Sasamori Takahiro, Tsurugi Hayato, Mashima Kazushi, Tokitoh Norihiro

ORGANOMETALLICS 36(7) 1224-1226 Apr 2017 [Refereed]

Germabenzenylpotassium: A Germanium Analogue of a Phenyl Anion

Mizuhata Yoshiyuki, Fujimori Shiori, Sasamori Takahiro, Tokitoh Norihiro

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56(16) 4588-4592 Apr 2017 [Refereed]

Asymmetric Intramolecular C-H Insertion Promoted by Dirhodium(II) Carboxylate Catalyst Bearing Axially Chiral Amino Acid Derivatives

Lu Wen-Jie, Pei Xu, Murai Takuya, Sasamori Takahiro, Tokitoh Norihiro, Kawabata Takeo, Furuta Takumi

SYNLETT 28(6) 679-683 Apr 2017 [Refereed]

Nature of E2X2 sigma(4c-6e) of the X---E-E---X type at naphthalene 1,8-positions and model, elucidated by X-ray crystallographic analysis and QC calculations with the QTAIM approach

Tsubomoto Yutaka, Hayashi Satoko, Nakanishi Waro, Sasamori Takahiro, Tokitoh Norihiro

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS 73(Pt 2) 265-275 Apr 2017 [Refereed]

Synthesis, Structure, and First Reactivity Studies of Functional (Phosphinoamino)boranes

Majhi Paresh Kumar, Franco Jose Manuel Villalba, Schnakenburg Gregor, Sasamori Takahiro, Streubel Rainer

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (5) 910-914 Feb 2017 [Refereed]

Skeletal Rearrangements of Polycyclic alpha-Ketols

Kawamura Moe, Kamo Shogo, Azuma Shuhei, Kubo Konomi, Sasamori Takahiro, Tokitoh Norihiro, Kuramochi Kouji, Tsubaki Kazunori

ORGANIC LETTERS 19(2) 301-303 Jan 2017 [Refereed]

The (oxalato)aluminate complex as an antimicrobial substance protecting the "shiro" of Tricholoma matsutake from soil micro-organisms

Nishino Katsutoshi, Shiro Misao, Okura Ryuki, Oizumi Kazuya, Fujita Toru, Sasamori Takahiro, Tokitoh Norihiro, Yamada Akiyoshi, Tanaka Chihiro, Yamaguchi Muneyoshi, Hiradate Syuntaro, Hirai Nobuhiro

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY 81(1) 102-111 Jan 2017 [Refereed]

Pyridinium 5-aminothiazoles: specific photophysical properties and vapochromism in halogenated solvents

Yamaguchi Kirara, Murai Toshiaki, Tsuchiya Yuki, Miwa Yohei, Kutsumizu Shoichi, Sasamori Takahiro, Tokitoh Norihiro

RSC ADVANCES 7(29) 18132-18135 2017 [Refereed]

Fabrication of Efficient Perovskite Solar Cells by a Solution Process Using a Complex of CH3NH3PbI3(dmf) as a Key Precursor

2017 24TH INTERNATIONAL WORKSHOP ON ACTIVE-MATRIX FLATPANEL DISPLAYS AND DEVICES (AM-FPD) 233-234 2017 [Refereed]

Reaction of a Stable Digermyne with Acetylenes: Synthesis of a 1,2-Digermabenzene and a 1,4-Digermabarrelene

Sugahara Tomohiro, Guo Jing-Dong, Sasamori Takahiro, Karatsu Yusaku, Furukawa Yukio, Espinosa Ferao Arturo, Nagase Shigeru, Tokitoh Norihiro

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 89(11) 1375-1384 Nov 2016 [Refereed]

Synthesis and Structure of an Iron-Bromoalumanyl Complex with a Tri-Coordinated Aluminum Center

Agou Tomohiro, Yanagisawa Tatsuya, Sasamori Takahiro, Tokitoh Norihiro

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 89(10) 1184-1186 Oct 2016 [Refereed]

Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species

Nagata Koichi, Murosaki Takahiro, Agou Tomohiro, Sasamori Takahiro, Matsuo Tsukasa, Tokitoh Norihiro

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55(41) 12877-12880 Oct 2016 [Refereed]

Acid-Responsive Absorption and Emission of 5-N-Arylaminothiazoles: Emission of White Light from a Single Fluorescent Dye and a Lewis Acid

Yamaguchi Kirara, Murai Toshiaki, Guo Jing-Dong, Sasamori Takahiro, Tokitoh Norihiro

CHEMISTRYOPEN 5(5) 434-438 Oct 2016 [Refereed]

Acid-Responsive Absorption and Emission of 5-N-Arylaminothiazoles: Emission of White Light from a Single Fluorescent Dye and a Lewis Acid.

Yamaguchi K, Murai T, Guo JD, Sasamori T, Tokitoh N

ChemistryOpen 5(5) 396 Oct 2016 [Refereed]

Isolation and Ambident Reactivity of a Chlorogermylenoid

Suzuki Yuko, Sasamori Takahiro, Guo Jing-Dong, Nagase Shigeru, Tokitoh Norihiro

CHEMISTRY-A EUROPEAN JOURNAL 22(39) 13784-13788 Sep 2016 [Refereed]

Synthesis of a 1-Aryl-2,2-chlorosilyl(phospha)silene Coordinated by an <em>N</em>-Heterocyclic Carbene

Kyri Andreas Wolfgang, Majhi Paresh Kumar, Sasamori Takahiro, Agou Tomohiro, Nesterov Vitaly, Guo Jing-Dong, Nagase Shigeru, Tokitoh Norihiro, Streubel Rainer

MOLECULES 21(10) Sep 2016 [Refereed]

Reactivities of a barrelene-type dialumane as an equivalent of an Al=Al doubly-bonded species

Agou Tomohiro, Nagata Koichi, Sasamori Takahiro, Tokitoh Norihiro

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 191(4) 588-590 Apr 2016 [Refereed]

Synthesis and properties of stable alumoles

Tokitoh Norihiro, Agou Tomohiro, Wasano Tatsuya, Sasamori Takahiro

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 191(4) 584-587 Apr 2016 [Refereed]

Computational Picture of Silyl Transfer from Silylsilatranes to Arylpalladium Chloride

Guo Jing-Dong, Sasamori Takahiro, Yamamoto Yutaro, Matsubara Hiroshi, Nagase Shigeru, Yorimitsu Hideki

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 89(2) 192-194 Feb 2016 [Refereed]

Synthesis and Structure of Lewis-Base-Free Phosphinoalumane Derivatives

Agou Tomohiro, Ikeda Shin, Sasamori Takahiro, Tokitoh Norihiro

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (5) 623-627 Feb 2016 [Refereed]

Selenium-Substituted Phosphaalkenes Obtained through 1,2-Elimination of Chlorosilanes from Selenenylchlorophosphines

Sasamori Takahiro, Franco Jose Manuel Villalba, Guo Jing-Dong, Sugamata Koh, Nagase Shigeru, Streubel Rainer, Tokitoh Norihiro

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (5) 678-684 Feb 2016 [Refereed]

Formation of a Diaminoalkyne Derivative by Dialumane-mediated Homocoupling of t-Butyl Isocyanide

Nagata Koichi, Agou Tdmohiro, Sasamori Takahiro, Tokitoh Norihiro

CHEMISTRY LETTERS 44(11) 1610-1612 Nov 2015 [Refereed]

5-N-Arylaminothiazoles as Highly Twisted Fluorescent Monocyclic Heterocycles: Synthesis and Characterization.

Yamaguchi K, Murai T, Hasegawa S, Miwa Y, Kutsumizu S, Maruyama T, Sasamori T, Tokitoh N

The Journal of organic chemistry 80(21) 10742-10756 Nov 2015 [Refereed]

Reaction of a diaryldigermyne with ethylene.

Sasamori T, Sugahara T, Agou T, Sugamata K, Guo JD, Nagase S, Tokitoh N

Chemical science 6(10) 5526-5530 Oct 2015 [Refereed]

Photochemical (E)-(Z) Isomerization of the P=C Double Bond in Triphospha[3]radialene-[M(CO)(5)] (M = W, Cr) Complexes

Sasamori Takahiro, Hirano Koki, Miyake Hideaki, Tokitoh Norihiro

CHEMISTRY LETTERS 44(9) 1240-1242 Sep 2015 [Refereed]

Ring Expansion to 1-Bromo-1-alumacyclonona-2,4,6,8-tetraene by Insertion of Two Alkyne Molecules into the Al-C Bonds

Agou Tomohiro, Wasano Tatsuya, Sasamori Takahiro, Guo Jing-Dong, Nagase Shigeru, Tokitoh Norihiro

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54(33) 9568-9571 Aug 2015 [Refereed]

SULFURIZATION OF 4,5,6-TRIPHOSPHA[3]RADIALENE

Miyake Hideaki, Sasamori Takahiro, Tokitoh Norihiro

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 190(8) 1247-1250 Aug 2015 [Refereed]

Stimuli-Responsive Frustrated Lewis-Pair-Type Reactivity of a Tungsten Iminoazaphosphiridine Complex

Franco Jose Manuel Villalba, Schnakenburg Gregor, Sasamori Takahiro, Espinosa Ferao Arturo, Streubel Rainer

CHEMISTRY-A EUROPEAN JOURNAL 21(27) 9650-9655 Jun 2015 [Refereed]

A Nonaromatic Thiophene-Fused Heptalene and Its Aromatic Dianion

Oshima Hiroya, Fukazawa Aiko, Sasamori Takahiro, Yamaguchi Shigehiro

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54(26) 7636-7639 Jun 2015 [Refereed]

Synthesis and Characterization of a 1,2-Digermabenzene

Sasamori Takahiro, Sugahara Tomohiro, Agou Tomohiro, Guo Jing-Dong, Nagase Shigeru, Streubel Rainer, Tokitoh Norihiro

ORGANOMETALLICS 34(11) 2106-2109 Jun 2015 [Refereed]

Synthesis, Photochemical Properties, and Cytotoxicities of 2H-Naphtho[1,2-b]pyran and Its Photodimers

Ota Motohiro, Sasamori Takahiro, Tokitoh Norihiro, Onodera Takefumi, Mizushina Yoshiyuki, Kuramochi Kouji, Tsubaki Kazunori

JOURNAL OF ORGANIC CHEMISTRY 80(11) 5687-5695 Jun 2015 [Refereed]

Syntheses, Structures, and Properties of Biphosphinines Tethered Aromatic pi-System

Nagahora Noriyoshi, Ogawa Tamaki, Honda Maki, Fujii Motomi, Tokumaru Hiroshi, Sasamori Takahiro, Shioji Kosei, Okuma Kentaro

CHEMISTRY LETTERS 44(5) 706-708 May 2015 [Refereed]

Unexpected photochemical reactions of 2-aryl-2-ethynyltrisilane derivative

Egawa Yasunobu, Mizuhata Yoshiyuki, Sasamori Takahiro, Tokitoh Norihiro

MAIN GROUP METAL CHEMISTRY 38(1-2) 51-55 Mar 2015 [Refereed]

Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers.

Villalba Franco JM, Sasamori T, Schnakenburg G, Espinosa Ferao A, Streubel R

Chemical communications (Cambridge, England) 51(18) 3878-3881 Mar 2015 [Refereed]

Oxidation of an allene compound bearing 1,8-dichloroacridene moieties and photolysis of the halogenated allene compound for the generation of triplet carbenes

Fuku-en Shin-ichi, Furukawa Ko, Sasamori Takahiro, Tokitoh Norihiro, Abe Manabu, Yamamoto Yohsuke

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 28(2) 79-87 Feb 2015 [Refereed]

Syntheses and structures of a stable gallole free of Lewis base coordination and its dianion

Agou Tomohiro, Wasano Tatsuya, Sasamori Takahiro, Tokitoh Norihiro

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 28(2) 104-107 Feb 2015 [Refereed]

SYNTHESIS OF 1,2-DIALKYNYLDISILANES INCORPORATED IN 10-MEMBERED-RING SYSTEM

Mizuhata Yoshiyuki, Egawa Yasunobu, Sasamori Takahiro, Tokitoh Norihiro

HETEROCYCLES 90(2) 1111-1123 Jan 2015 [Refereed]

Going for strain: synthesis of the first 3-iminoazaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers

Franco Jose Manuel Villalba, Sasamori Takahiro, Schnakenburg Gregor, Espinosa Ferao Arturo, Streubel Rainer

CHEMICAL COMMUNICATIONS 51(18) 3878-3881 2015 [Refereed]

Reaction of a diaryldigermyne with ethylene

Sasamori Takahiro, Sugahara Tomohiro, Agou Tomohiro, Sugamata Koh, Guo Jing-Dong, Nagase Shigeru, Tokitoh Norihiro

CHEMICAL SCIENCE 6(10) 5526-5530 2015 [Refereed]

Syntheses and Structures of Stable 1-Aminoalumole Derivatives

Agou Tomohiro, Wasano Tatsuya, Sasamori Takahiro, Tokitoh Norihiro

ORGANOMETALLICS 33(23) 6963-6966 Dec 2014 [Refereed]

Isolation and Structural Characterization of a Lewis Base-Free Monolithioferrocene

Sasamori Takahiro, Suzuki Yuko, Tokitoh Norihiro

ORGANOMETALLICS 33(22) 6696-6699 Nov 2014 [Refereed]

Bromination of a Stable 1,2-Bis(ferrocenyl) dibismuthene: Synthesis of a 1,2-Dibromodibismuthane Derivative

Sasamori Takahiro, Sakagami Michiyasu, Tokitoh Norihiro

HETEROATOM CHEMISTRY 25(5) 306-312 Nov 2014 [Refereed]

The Synthesis and Properties of Bimetallic d-pi Electron Systems Containing Metallocenyl Substituents of Fe or Ru, and pi-Electron Spacers of Heavier Main Group Elements from Group 14 or 15

Sasamori Takahiro

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN 72(11) 1279-1289 Nov 2014 [Refereed]

Reaction of a Dialumene-Benzene Adduct with Diphenylacetylene: Formation of 3,4-Dialuminacyclobutene and 5,6-Dialuminabicyclo[2.1.1]hex-2-ene Derivatives

Agou Tomohiro, Nagata Koichi, Sasamori Takahiro, Tokitoh Norihiro

CHEMISTRY-AN ASIAN JOURNAL 9(11) 3099-3101 Nov 2014 [Refereed]

Synthesis, Structures, and Electronic Properties of Triple- and Double-Decker Ruthenocenes Incorporated by a Group 14 Metallole Dianion Ligand

Kuwabara Takuya, Guo Jing-Dong, Nagase Shigeru, Sasamori Takahiro, Tokitoh Norihiro, Saito Masaichi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136(37) 13059-13064 Sep 2014 [Refereed]

Structure of Stable Telluradiphosphirane Bearing Bulky Ferrocenyl Ligands

Sasamori Takahiro, Suzuki Yuko, Sakagami Michiyasu, Miyake Hideaki, Tokitoh Norihiro

CHEMISTRY LETTERS 43(9) 1464-1466 Sep 2014 [Refereed]

Synthesis, structure and reactivity of a 1-bromoalumole

Wasano Tatsuya, Agou Tomohiro, Sasamori Takahiro, Tokitoh Norihiro

CHEMICAL COMMUNICATIONS 50(60) 8148-8150 Aug 2014 [Refereed]

Reactions of Diaryldibromodisilenes with N-Heterocyclic Carbenes: Formation of Formal Bis-NHC Adducts of Silyliumylidene Cations

Agou Tomohiro, Hayakawa Naoki, Sasamori Takahiro, Matsuo Tsukasa, Hashizume Daisuke, Tokitoh Norihiro

CHEMISTRY-A EUROPEAN JOURNAL 20(30) 9246-9249 Jul 2014 [Refereed]

Facile Synthesis of Dibenzopentalene Dianions and Their Application as New pi-Extended Ligands

Kuwabara Takuya, Ishimura Kazuya, Sasamori Takahiro, Tokitoh Norihiro, Saito Masaichi

CHEMISTRY-A EUROPEAN JOURNAL 20(25) 7571-7575 Jun 2014 [Refereed]

On-Top pi-Stacking of Quasiplanar Molecules in Hole-Transporting Materials: Inducing Anisotropic Carrier Mobility in Amorphous Films

Wakamiya Atsushi, Nishimura Hidetaka, Fukushima Tatsuya, Suzuki Furitsu, Saeki Akinori, Seki Shu, Osaka Itaru, Sasamori Takahiro, Murata Michihisa, Murata Yasujiro, Kaji Hironori

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53(23) 5800-5804 Jun 2014 [Refereed]

Reproducible Fabrication of Efficient Perovskite-based Solar Cells: X-ray Crystallographic Studies on the Formation of CH3NH3PbI3 Layers

Wakamiya Atsushi, Endo Masaru, Sasamori Takahiro, Tokitoh Norihiro, Ogomi Yuhei, Hayase Shuzi, Murata Yasujiro

CHEMISTRY LETTERS 43(5) 711-713 May 2014 [Refereed]

A Convenient Route to Synthetic Analogues of the Oxidized Form of High-Potential Iron-Sulfur Proteins

Tanifuji Kazuki, Yamada Norihiro, Tajima Tomoyuki, Sasamori Takahiro, Tokitoh Norihiro, Matsuo Tsukasa, Tamao Kohei, Ohki Yasuhiro, Tatsumi Kazuyuki

INORGANIC CHEMISTRY 53(8) 4000-4009 Apr 2014 [Refereed]

Synthesis of a Rhodium Carbonyl Phosphaalkenyl-Phosphido Complex: A Phosphorus Congener of Schiff Base Type N,N '-Chelating Monoanionic Ligands

Matsumoto Teruyuki, Sasamori Takahiro, Miyake Hideaki, Tokitoh Norihiro

ORGANOMETALLICS 33(6) 1341-1344 Mar 2014 [Refereed]

Synthesis and Structure of a 1-Phospha-2-boraacenaphthene Derivative and Its Chalcogenation Reactions

Tsurusaki Akihiro, Sasamori Takahiro, Tokitoh Norihiro

CHEMISTRY-A EUROPEAN JOURNAL 20(13) 3752-3758 Mar 2014 [Refereed]

Synthesis and Properties of Butterfly-Shaped Expanded Naphthofuran Derivatives

Nakanishi Kentaro, Sasamori Takahiro, Kuramochi Kouji, Tokitoh Norihiro, Kawabata Takeo, Tsubaki Kazunori

JOURNAL OF ORGANIC CHEMISTRY 79(6) 2625-2631 Mar 2014 [Refereed]

Oxidative kinetic resolution of racemic alkyl aryl carbinols by an electronically tuned chiral nitroxyl radical

Hamada Shohei, Wada Yoshiyuki, Sasamori Takahiro, Tokitoh Norihiro, Furura Takumi, Kawabata Takeo

TETRAHEDRON LETTERS 55(11) 1943-1945 Mar 2014 [Refereed]

Planar Chiral Tetrasubstituted [2.2]Paracyclophane: Optical Resolution and Functionalization

Morisaki Yasuhiro, Gon Masayuki, Sasamori Takahiro, Tokitoh Norihiro, Chujo Yoshiki

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136(9) 3350-3353 Mar 2014 [Refereed]

Synthesis and Characterization of Binary-Complex Models of Ureas and 1,3-Dicarbonyl Compounds: Deeper Insights into Reaction Mechanisms Using Snap-Shot Structural Analysis

Azuma Takumi, Kobayashi Yusuke, Sakata Ken, Sasamori Takahiro, Tokitoh Norihiro, Takemoto Yoshiji

JOURNAL OF ORGANIC CHEMISTRY 79(4) 1805-1817 Feb 2014 [Refereed]

Unique Synthetic Approach toward a Phosphaalkene: Synthesis of a Selenium-substituted Phosphaalkene with Bulky Substituents

Sugamata Koh, Sasamori Takahiro, Tokitoh Norihiro

CHEMISTRY LETTERS 43(1) 95-96 Jan 2014 [Refereed]

Dimerization Reactions of 2-Bromo-3,5,6-trimethyl-1,4-benzoquinone

Azuma Shuhei, Ota Motohiro, Ishida Akito, Isozaki Katsuhiro, Takaya Hikaru, Nakamura Masaharu, Sasamori Takahiro, Tokitoh Norihiro, Kuramochi Kouji, Tsubaki Kazunori

CHEMISTRY LETTERS 42(12) 1531-1533 Dec 2013 [Refereed]

Step-wise sulfurization of stable 1,2-bis(ferrocenyl)diphosphene

Sasamori Takahiro, Sakagami Michiyasu, Tokitoh Norihiro

JOURNAL OF SULFUR CHEMISTRY 34(6) 677-683 Dec 2013 [Refereed]

A Cyclochiral Conformational Motif Constructed Using a Robust Hydrogen-Bonding Network (vol 135, pg 13644, 2013)

Mishiro Kenji, Furuta Takumi, Sasamori Takahiro, Hayashi Kazuhiro, Tokitoh Norihiro, Futaki Shiroh, Kawabata Takeo

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 135(45) 17236 Nov 2013 [Refereed]

1,2-Bis(ferrocenyl)dipnictenes: Bimetallic Systems with a Pn=Pn Heavy pi-Spacer (Pn: P, Sb, and Bi)

Sakagami Michiyasu, Sasamori Takahiro, Sakai Heisuke, Furukawa Yukio, Tokitoh Norihiro

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 86(10) 1132-1143 Oct 2013 [Refereed]

A Cyclochiral Conformational Motif Constructed Using a Robust Hydrogen-Bonding Network

Mishiro Kenji, Furuta Takumi, Sasamori Takahiro, Hayashi Kazuhiro, Tokitoh Norihiro, Futaki Shiroh, Kawabata Takeo

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 135(37) 13644-13647 Sep 2013 [Refereed]

A New Family of Multiple-Bond Compounds between Heavier Group 14 Elements

Sasamori Takahiro, Tokitoh Norihiro

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 86(9) 1005-1021 Sep 2013 [Refereed]

Expansion of Orifices of Open C-60 Derivatives and Formation of an Open C59S Derivative by Reaction with Sulfur

Futagoishi Tsukasa, Murata Michihisa, Wakamiya Atsushi, Sasamori Takahiro, Murata Yasujiro

ORGANIC LETTERS 15(11) 2750-2753 Jun 2013 [Refereed]

Investigation of the Carboxylate Position during the Acylation Reaction Catalyzed by Biaryl DMAP Derivatives with an Internal Carboxylate

Nishino Reiko, Furuta Takumi, Kan Keizo, Sato Makoto, Yamanaka Masahiro, Sasamori Takahiro, Tokitoh Norihiro, Kawabata Takeo

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52(25) 6445-6449 Jun 2013 [Refereed]

Biomimetic Synthesis of Zeylanone and Zeylanone Epoxide by Dimerization of 2-Methyl-1,4-naphthoquinone

Maruo Sayako, Nishio Kazuyuki, Sasamori Takahiro, Tokitoh Norihiro, Kuramochi Kouji, Tsubaki Kazunori

ORGANIC LETTERS 15(7) 1556-1559 Apr 2013 [Refereed]

1,2-Bis(ferrocenyl)-Substituted Distibene and Dibismuthene: Sb=Sb and Bi=Bi Units as pi Spacers between Two Ferrocenyl Units

Sakagami Michiyasu, Sasamori Takahiro, Sakai Heisuke, Furukawa Yukio, Tokitoh Norihiro

CHEMISTRY-AN ASIAN JOURNAL 8(4) 690-693 Apr 2013 [Refereed]

Borylated Dibenzoborepin: Synthesis by Skeletal Rearrangement and Photochromism Based on Bora-Nazarov Cyclization

Iida Azusa, Saito Shohei, Sasamori Takahiro, Yamaguchi Shigehiro

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52(13) 3760-3764 Mar 2013 [Refereed]

ASYMMETRIC INTRAMOLECULAR CONJUGATE ADDITION OF alpha-AMINO ACID DERIVATIVES VIA RACEMIZATION-FREE EQUILIBRIUM OF INTERMEDIARY CHIRAL ENOLATES

Monguchi Daiki, Yoshimura Tomoyuki, Irie Kazuyuki, Hayashi Kazuhiro, Majumdar Swapan, Sasamori Takahiro, Tokitoh Norihiro, Kawabata Takeo

HETEROCYCLES 86(2) 1483-1494 Dec 2012 [Refereed]

The 4,5,6-triphospha[3]radialene dianion: a phosphorus analogue of the deltate dianion. A NICS(0)(pi zz) examination of their aromaticity

Miyake Hideaki, Sasamori Takahiro, Wu Judy I-Chia, Schleyer Paul V. R., Tokitoh Norihiro

CHEMICAL COMMUNICATIONS 48(93) 11440-11442 Dec 2012 [Refereed]

Protonation-Assisted Conjugate Addition of Axially Chiral Enolates: Asymmetric Synthesis of Multisubstituted beta-Lactams from alpha-Amino Acids

Yoshimura Tomoyuki, Takuwa Masatoshi, Tomohara Keisuke, Uyama Makoto, Hayashi Kazuhiro, Yang Pan, Hyakutake Ryuichi, Sasamori Takahiro, Tokitoh Norihiro, Kawabata Takeo

CHEMISTRY-A EUROPEAN JOURNAL 18(48) 15330-15336 Nov 2012 [Refereed]

Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene

Sasamori Takahiro, Sakagami Michiyasu, Niwa Masatoshi, Sakai Heisuke, Furukawa Yukio, Tokitoh Norihiro

CHEMICAL COMMUNICATIONS 48(68) 8562-8564 Sep 2012 [Refereed]

1,2-Bis(ferrocenyl)digermene: A d-pi Electron System Containing a Ge=Ge Unit

Sasamori Takahiro, Miyamoto Hisashi, Sakai Heisuke, Furukawa Yukio, Tokitoh Norihiro

ORGANOMETALLICS 31(10) 3904-3910 May 2012 [Refereed]

Three Different Dimerizations of 2-Bromo-3-methyl-1,4-naphthoquinones

Azuma Shuhei, Nishio Kazuyuki, Kubo Konomi, Sasamori Takahiro, Tokitoh Norihiro, Kuramochi Kouji, Tsubaki Kazunori

JOURNAL OF ORGANIC CHEMISTRY 77(10) 4812-4820 May 2012 [Refereed]

Misc

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Synthesis of the First Stable Bismuth Antimony Double-bond Compound (poster)

N. Takeda ,N. Takeda, T. Sasamori, N. Tokitoh

The 8th International Kyoto Conference on New Aspects of Organic Chemistry ,京都 Jul 2000 [Refereed]

Novel Disproportionation Reaction of stable Stibabismuthene via 1,2,3,4-Distibadibismetane Derivative (Poster)

N. Tokitoh ,N. Tokitoh, T. Sasamori., N. Takeda (Graduate School of Science, Kyushu University, Institute for Chemical Research, Kyoto University)

The 9th International Conference on Inorganic Ring Systems ,University of Saarland, Saarbrcken, Germany Jul 2000 [Refereed]

Synthesis and structure of a stable 1,3-dihydro-2-ferrocenyltriphosphane and its thermal decomposition giving a ferrocenyl diphosphene(poster)

N. Nagahora (Kyoto Univ.) ,N. Nagahora; T. Sasamori; N. Takeda; N. Tokitoh

2005 International Chemical Congress of Pacific Basin Societies (Pacifichem 2005) ,Honolulu, Hawaii, USA Dec 2000 [Refereed]

Extended hypervalent C-Z---O---Z-C (Z = O, S and Se) 5c-6e bonds in anthraquinone system: Structural, spectroscopic and theoretical investigations (poster)

T. Nakamoto (Wakayama Univ.) ,T. Nakamoto; S. Hayashi; W. Nakanishi; T. Sasamori; N. Tokitoh (Wakayama Univ. & Kyoto Univ.)

2005 International Chemical Congress of Pacific Basin Societies (Pacifichem 2005) ,Honolulu, Hawaii, USA Dec 2000 [Refereed]

Reactions of kinetically stabilized doubly-bonded systems between heavier group 15 elements

T. Sasamori (Kyoto Univ.) ,T. Sasamori; E. Mieda; N. Nagahora; N. Takeda; N. Tokitoh(Kyoto Univ.)

2005 International Chemical Congress of Pacific Basin Societies (Pacifichem 2005) ,Honolulu, Hawaii, USA Dec 2000 [Refereed]

Conference Activities & Talks

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Synthesis and Structure of a Stable Bis(methylene)-λ⁴-sulfane

K. Sugamata, D. Hashizume, Y. Suzuki, T. Sasamori, S. Ishii, Y. Urao, M. Minoura

28th International Symposium on the Organic Chemistry of Sulfur (ISOCS-28) 2018

Synthesis of Biaryls from Aryl Sulfoxides and Anilines via Sigmatropic Rearrangement

T. Yanagi, G. Jing-Dong, K. Nogi, T. Sasamori, H. Yorimitsu

28th International Symposium on the Organic Chemistry of Sulfur (ISOCS-28) 2018

Chalcogenation Reactions of 1,2-Digermacyclobutadiene

T. Sugahara, T. Sasamori, N. Tokitoh

28th International Symposium on the Organic Chemistry of Sulfur (ISOCS-28) 2018

Synthesis and Properties of Stable 1,4-Digermabenzenes

T. Sugahara, J.-D. Guo, T. Sasamori, N. Tokitoh

The 15th International Symposium on Inorganic Ring Systems (IRIS-15) 2018

Synthesis of A Cyclic 1,3-Digerma-2-silaallene: A Cyclic Silylone

T. Sasamori

The 15th International Symposium on Inorganic Ring Systems (IRIS-15) 2018

Association Memberships

Royal Society of Chemistry(59) , The Chemical Society of Japan(2583) , The KINNKI Chemical Society(1) , The Society of Silicon Chemistry(5) , The Society of Synthetic Organic Chemistry(89)

Research Grants & Projects

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JSPS: KIBAN (B)

Project Year: 2015 - 2017 Investigator(s): SASAMORI Takahiro

JSPS: WAKATE (A)

Project Year: 2011 - 2013 Investigator(s): SASAMORI Takahiro

JSPS: WAKATE (B)

Project Year: 2006 - 2007 Investigator(s): SASAMORI Takahiro

JSPS: WAKATE (B)

Project Year: 2004 - 2005 Investigator(s): SASAMORI Takahiro

JSPS: DC1

Project Year: 1999 - 2001 Investigator(s): SASAMORI Takahiro