2020年6月
1,2-Insertion reactions of alkynes into Ge-C bonds of arylbromogermylene
DALTON TRANSACTIONS
- 巻
- 49
- 号
- 21
- 開始ページ
- 7189
- 終了ページ
- 7196
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/d0dt01223h
- 出版者・発行元
- ROYAL SOC CHEMISTRY
1,2-Insertion reactions of alkynes into the Ge-C bonds in dibromodigermenes afford stable crystalline bromovinylgermylenes. In contrast to previously reported Lewis-base-supported vinylgermylenes, the bromovinylgermylene obtained from reaction of the bromogermylene with 3-hexyne via such an 1,2-insertion is a donor-free monomer. A feasible reaction mechanism, proposed on the basis of the observed experimental results in combination with theoretical calculations, suggests that the [1+2]-cycloadduct and the insertion product are the kinetic and thermodynamic product, respectively.
- リンク情報
-
- DOI
- https://doi.org/10.1039/d0dt01223h
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/32415829
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000538134300030&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85085640247&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85085640247&origin=inward
- ID情報
-
- DOI : 10.1039/d0dt01223h
- ISSN : 1477-9226
- eISSN : 1477-9234
- PubMed ID : 32415829
- SCOPUS ID : 85085640247
- Web of Science ID : WOS:000538134300030