論文

査読有り
2012年

Crystal structure refinement of Cu6O8YCl by powder neutron diffraction

Journal of Physics: Conference Series
  • Kenji Kawashima
  • ,
  • Kazumasa Horigane
  • ,
  • Kenji Ohoyama
  • ,
  • Jun Akimitsu

391
1
記述言語
英語
掲載種別
研究論文(国際会議プロシーディングス)
DOI
10.1088/1742-6596/391/1/012129
出版者・発行元
Institute of Physics Publishing

We report the crystal structure parameters of clathrate-type copper-oxide Cu6O8YCl, which belongs to the Cu6O8MX (M cation, X anion) family, investigated by the powder neutron diffraction technique and the Rietveld method. The crystal structure of Cu6O8YCl was identified to be a cubic structure with the space group Fmm. The Cl atom is located at the 4a site, which is the center position of the Cu6O8 cage, and the Y atom occupies the 4b site in the cuboid space. The Y and Cl atoms have anomalously large atomic displacement parameters (Uiso) at room temperature, which suggests that Y and Cl atoms respectively present in a cuboid and in a Cu6O8 cage exhibit intensive motion such as rattling, as recently observed for clathrate compounds. © Published under licence by IOP Publishing Ltd.

リンク情報
DOI
https://doi.org/10.1088/1742-6596/391/1/012129
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84874905485&origin=inward
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=84874905485&origin=inward
ID情報
  • DOI : 10.1088/1742-6596/391/1/012129
  • ISSN : 1742-6596
  • ISSN : 1742-6588
  • eISSN : 1742-6596
  • SCOPUS ID : 84874905485

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