論文

査読有り
2015年8月

Hydrogen self-diffusivity in single crystal ringwoodite: Implications for water content and distribution in the mantle transition zone

GEOPHYSICAL RESEARCH LETTERS
  • Wei Sun
  • ,
  • Takashi Yoshino
  • ,
  • Naoya Sakamoto
  • ,
  • Hisayoshi Yurimoto

42
16
開始ページ
6582
終了ページ
6589
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/2015GL064486
出版者・発行元
AMER GEOPHYSICAL UNION

Hydrogen lattice diffusion in Fe-bearing ringwoodite was investigated through hydrogen and deuterium interdiffusing in a pair of synthesized single crystals at various temperatures (1000-1300 K) at 21 GPa. Diffusion profiles were investigated by secondary ion mass spectrometer to determine the hydrogen self-diffusivity in ringwoodite. Temperature dependences of hydrogen diffusion in ringwoodite were determined to be D-H=10(-7.29(+/- 0.46)) exp[-101(+/- 10) kJ mol(-1)/RT] m(2)/s in ringwoodite at 21GPa. The proton conductivities of ringwoodite estimated from the present diffusion coefficients are similar to those of Yoshino et al. [2008] at the transition zone condition at low water content (<1000 ppm by weight (ppmw)) but lower at higher water content range (>1000 ppmw). If the proton-vacancy mechanism is assumed to be a main controlling mechanism, contribution of water to the electrical conductivity of ringwoodite is insignificant due to large contribution of hopping conduction at the transition zone condition, and global average water concentration in the lower part of transition zone is less than 1000 ppmw.

リンク情報
DOI
https://doi.org/10.1002/2015GL064486
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000363410800007&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-84941747743&partnerID=MN8TOARS
URL
http://orcid.org/0000-0002-5422-7396
ID情報
  • DOI : 10.1002/2015GL064486
  • ISSN : 0094-8276
  • eISSN : 1944-8007
  • ORCIDのPut Code : 58517948
  • SCOPUS ID : 84941747743
  • Web of Science ID : WOS:000363410800007

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