Papers

Peer-reviewed
Jan, 2020

Grain boundary diffusion of W in lower mantle phase with implications for isotopic heterogeneity in oceanic island basalts by core-mantle interactions

Earth and Planetary Science Letters
  • T. Yoshino
  • ,
  • Y. Makino
  • ,
  • T. Suzuki
  • ,
  • T. Hirata

Volume
530
Number
First page
115887
Last page
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1016/j.epsl.2019.115887
Publisher
ELSEVIER

Tungsten isotopes provide important constraints on the ocean-island basalt (OIB) source regions. Recent analyses of mu W-182 in modern basalts with high He-3/He-4 originating from the core-mantle boundary region reveal two distinct features: positive mu W-182 in Phanerozoic flood basalts indicating the presence of primordial reservoir, and negative mu W-182 in modern OlBs. One possibility to produce large variations in mu W-182 is interaction between the mantle and outer core. Here, we report grain boundary diffusion of W in lower mantle phases. High pressure experimental results show that grain boundary diffusion of W is fast and strongly temperature dependent. Over Earth's history, diffusive transport of W from the core to the lowermost mantle may have led to significant modification of the W isotopic composition of the lower mantle at length scales exceeding one kilometer. Such grain boundary diffusion can lead to large variations in mu W-182 in modern basalts as a function of the distance of their source regions from the core mantle boundary. Modern oceanic island basalts from Hawaii, Samoa and Iceland exhibit negative mu W-182 and likely originated from the modified isotope region just above the core-mantle boundary, whereas those with positive mu W-182 could be derived from the thick Large Low Shear Velocity Provinces (LLSVPs) far from the core-mantle boundary (CMB). When highly-oxidized slabs accumulate at the CMB oxidizing the outer core at the interface, a large W flux with negative mu W-182 can be added to the silicate mantle. As a result, the source region of the mu W-182 would be effectively modified to a negative mu W-182. (C) 2019 Elsevier B.V. All rights reserved.

Link information
DOI
https://doi.org/10.1016/j.epsl.2019.115887
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000508747300021&DestApp=WOS_CPL
ID information
  • DOI : 10.1016/j.epsl.2019.115887
  • ISSN : 0012-821X
  • eISSN : 1385-013X
  • Web of Science ID : WOS:000508747300021

Export
BibTeX RIS