Jan, 2020
Grain boundary diffusion of W in lower mantle phase with implications for isotopic heterogeneity in oceanic island basalts by core-mantle interactions
Earth and Planetary Science Letters
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- Volume
- 530
- Number
- First page
- 115887
- Last page
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1016/j.epsl.2019.115887
- Publisher
- ELSEVIER
Tungsten isotopes provide important constraints on the ocean-island basalt (OIB) source regions. Recent analyses of mu W-182 in modern basalts with high He-3/He-4 originating from the core-mantle boundary region reveal two distinct features: positive mu W-182 in Phanerozoic flood basalts indicating the presence of primordial reservoir, and negative mu W-182 in modern OlBs. One possibility to produce large variations in mu W-182 is interaction between the mantle and outer core. Here, we report grain boundary diffusion of W in lower mantle phases. High pressure experimental results show that grain boundary diffusion of W is fast and strongly temperature dependent. Over Earth's history, diffusive transport of W from the core to the lowermost mantle may have led to significant modification of the W isotopic composition of the lower mantle at length scales exceeding one kilometer. Such grain boundary diffusion can lead to large variations in mu W-182 in modern basalts as a function of the distance of their source regions from the core mantle boundary. Modern oceanic island basalts from Hawaii, Samoa and Iceland exhibit negative mu W-182 and likely originated from the modified isotope region just above the core-mantle boundary, whereas those with positive mu W-182 could be derived from the thick Large Low Shear Velocity Provinces (LLSVPs) far from the core-mantle boundary (CMB). When highly-oxidized slabs accumulate at the CMB oxidizing the outer core at the interface, a large W flux with negative mu W-182 can be added to the silicate mantle. As a result, the source region of the mu W-182 would be effectively modified to a negative mu W-182. (C) 2019 Elsevier B.V. All rights reserved.
- Link information
- ID information
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- DOI : 10.1016/j.epsl.2019.115887
- ISSN : 0012-821X
- eISSN : 1385-013X
- Web of Science ID : WOS:000508747300021