2016年8月
Ambient-Temperature Spin-State Switching Achieved by Protonation of the Amino Group in [Fe(H(2)Bpz(2))(2)(bipy-NH2)]
INORGANIC CHEMISTRY
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- 巻
- 55
- 号
- 16
- 開始ページ
- 8147
- 終了ページ
- 8152
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1021/acs.inorgchem.6b01193
- 出版者・発行元
- AMER CHEMICAL SOC
Magnetism of a complex [Fe(H(2)Bpz(2))(2)(bipy-NH2)] (H(2)Bpz(2) = dihydrobis(1-pyrazolypborate, bipy-NH2 = 4,4'-diamino-2,2'-bipyridine) has been altered from paramagnetic to spin-crossover (SCO) behavior, through protonation of one amino group of bipy-NH2 with CF3SO3H. Complete SCO transition, both in solid state and in solution, occurs at ambient temperature.
- リンク情報
- ID情報
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- DOI : 10.1021/acs.inorgchem.6b01193
- ISSN : 0020-1669
- eISSN : 1520-510X
- Web of Science ID : WOS:000381594100044