2006年5月
Redox behavior and catalytic oxidation reactions of alcohols by a new ruthenium(III)-dioxolene-amine complex of bis(2-pyridylmethyl)-2-aminoethylamine
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
- ,
- ,
- 巻
- 79
- 号
- 5
- 開始ページ
- 745
- 終了ページ
- 747
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1246/bcsj.79.745
- 出版者・発行元
- CHEMICAL SOC JAPAN
A ruthenium-dioxolene-amine complex, [Ru-III(NH2L)(Bu(2)sq)](PF6)(2)center dot 0.5H(2)O (NH2-L = bis(2-pyridylmethyl)2-aminoethylamine, Bu(2)sq(-) = 15-di-tert-butylsemiquinonate). was newly prepared. The complex undergoes spontaneous one-electron reduction under basic conditions in MeOH and works as an electrocatalyst in the oxidation of benzyl alcohol to benzaldehyde under electrolysis at +0.4V (vs SCE).
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.79.745
- ISSN : 0009-2673
- eISSN : 1348-0634
- Web of Science ID : WOS:000238183400010