2011年3月
Nature of Electron Transport by Pyridine-Based Tripodal Anchors: Potential for Robust and Conductive Single-Molecule Junctions with Gold Electrodes
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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- 巻
- 133
- 号
- 9
- 開始ページ
- 3014
- 終了ページ
- 3022
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ja109577f
- 出版者・発行元
- AMER CHEMICAL SOC
We have designed and synthesized a pyridine-based tripodal anchor unit to construct a single-molecule junction with a gold electrode. The advantage of tripodal anchoring to a gold surface was unambiguously demonstrated by cyclic voltanunetry measurements. X-ray photoelectron spectroscopy measurements indicated that the A orbital of pyridine contributes to the physical adsorption of the tripodal anchor unit to the gold surface, The conductance of a single-molecule junction that consists of the tripodal anchor and diphenyl acetylene was measured by modified scanning tunneling microscope techniques and successfully determined to be 5 +/- 1 x 10(-4) G(0.) Finally, by analyzing the transport mechanism based on ab initio calculations, the participation of the pi orbital of the anchor moieties was predicted. The tripodal structure is expected to form a robust junction, and pyridine is predicted to achieve pi-channel electric transport.
- リンク情報
- ID情報
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- DOI : 10.1021/ja109577f
- ISSN : 0002-7863
- ORCIDのPut Code : 38500476
- Web of Science ID : WOS:000289455200039