論文

査読有り
2016年

Solvent effects on the fracture of chemically crosslinked gels

SOFT MATTER
  • Yoshimi Tanaka
  • ,
  • Risa Shimazaki
  • ,
  • Satoshi Yano
  • ,
  • Gaku Yoshida
  • ,
  • Tetsuo Yamaguchi

12
39
開始ページ
8135
終了ページ
8142
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/c6sm01645f
出版者・発行元
ROYAL SOC CHEMISTRY

We have investigated how the fracture behavior of a polyacrylamide hydrogel is affected by different types of solvents poured into its crack tips. We obtained the following results: first, when water (good solvent or reaction solvent for the polyacrylamide gel) is poured, the fracture energy Gamma becomes smaller than that measured in air for small crack velocities V (V <= 10 mm s(-1)). Second, when good solvents other than water are poured, Gamma is enhanced for a large V region (5 <= V <= 60 mm s(-1)), but this effect is not observed for smaller V; Gamma(V) in good solvents converges to that in water as V -> 0. Third, when ethanol (poor solvent for polyacrylamide) is poured, stick-slip-like crack propagation appears in the entire V range, and Gamma calculated from the time-average of the oscillating tearing forces is larger than that in air or in other solvents. We discuss the results on the basis of diffusion dynamics around the crack tips of the gel.

リンク情報
DOI
https://doi.org/10.1039/c6sm01645f
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/27714362
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000385489100008&DestApp=WOS_CPL
ID情報
  • DOI : 10.1039/c6sm01645f
  • ISSN : 1744-683X
  • eISSN : 1744-6848
  • PubMed ID : 27714362
  • Web of Science ID : WOS:000385489100008

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