2010年2月
Moisture driven aging mechanism of LiFePO4 subjected to air exposure
ELECTROCHEMISTRY COMMUNICATIONS
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- 巻
- 12
- 号
- 2
- 開始ページ
- 238
- 終了ページ
- 241
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/j.elecom.2009.12.003
- 出版者・発行元
- ELSEVIER SCIENCE INC
The impact of air exposure on LiFePO4-C nanocomposites has been investigated at moderate temperature. We show here that the storage in 120 degrees C hot air for 30 days leads not only to the material delithiation but also to the formation of an amorphous ferric phosphate side-phase, accounting for 38% of the total iron. The formed phase is found to be partially hydrated, suggesting a water-driven aging mechanism and a proposed hypothetic formula: LixFePO4(OH)(x). The side-phase displays new electrochemical activity but poor cyclability and the overall battery performance is thus deteriorated. The regeneration of pristine structure, together with the performance recovery can be achieved by a simple thermal treatment under inert atmosphere. (C) 2009 Elsevier B.V. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.elecom.2009.12.003
- ISSN : 1388-2481
- Web of Science ID : WOS:000274878400017