2006年4月
Wide electrochemical window at the interface between water and a hydrophobic room-temperature ionic liquid of tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
ANALYTICAL CHEMISTRY
- ,
- ,
- 巻
- 78
- 号
- 8
- 開始ページ
- 2726
- 終了ページ
- 2731
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ac052152o
- 出版者・発行元
- AMER CHEMICAL SOC
Ionic liquids composed of a hydrophobic anion, tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (TFPB-), and various aromatic and aliphatic ammonium have been prepared. TFPB salts of N-octadecylisoquinolinium (C(18)Iq(+)) and trioctylmethylammonium (TOMA(+)) show low melting points of 31 and 36 degrees C, respectively, whereas TFPB-based ionic liquids of 1-alkyl-3-methylimidazolium with the alkyl chain length of 5-12 show melting points lower than 90 degrees C. The [C(18)Iq][TFPB]vertical bar water (W) and [TOMA][TFPB]vertical bar W interfaces have the polarized potential window (ppw) of 0.8 V at 56 T, which is twice as wide as the ppw at the interface between W and room-temperature ionic liquids of bis(perfluoroalkylsulfonyl)imide so far reported. The extension of the ppw by more than 0.4 V to the positive direction enables voltammetric measurements of the ion transfer of relatively hydrophobic anions such as bis(trifluoromethylsulfonyl)imide and bis(pentafluoroethylsulfionyl)imide and of hydrophilic cations such as tetraethylammonium and acetylcholine ions.
- リンク情報
- ID情報
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- DOI : 10.1021/ac052152o
- ISSN : 0003-2700
- Web of Science ID : WOS:000236948300034