2019年3月
Polymer-Supported Terpyridine–Palladium Complex for the Allylic Alkylation with Arylboronic Acid in Water
Transactions of the Materials Research Society of Japan
- ,
- ,
- ,
- ,
- 巻
- 44
- 号
- 1
- 開始ページ
- 41
- 終了ページ
- 44
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.14723/tmrsj.44.41
- 出版者・発行元
- 一般社団法人 日本MRS
<p> A novel homogeneous transition-metal catalyst, a polymer-supported terpyridine–palladium(II) complex, was found to promote the allylic alkylation with phenylborinic acid under phosphine-free conditions in water with good yield. The catalyst was recovered and reused several times without loss of catalytic activity. To our knowledge, this is the first example of the allylic alkylation with pheylboronic acid in water using a polymer-supported terpyridine–palladium(II) complex under aerobic conditions. The stereochemistry of the allylic alkylation with phenylboronic acid was demonstrated to be not net retention. </p>
- リンク情報
- ID情報
-
- DOI : 10.14723/tmrsj.44.41
- ISSN : 1382-3469
- CiNii Articles ID : 130007585617