2003年6月
Fluoride-induced chemiluminescent decomposition of dioxetanes bearing a siloxyaryl moiety to produce an alkyl aryl ketone as an emitter
TETRAHEDRON
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- 巻
- 59
- 号
- 26
- 開始ページ
- 4811
- 終了ページ
- 4819
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/S0040-4020(03)00727-0
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
Tetrabutylammonium fluoride induces the decomposition of 1-tert-butyl-4,4-dimethyl-5-(3-siloxyphenyl)-2,6,7-trioxabicyclo[3.2.0]heptane (4a) in DMSO to form an oxyanion of aromatic ketone (14a) as an emitter with high singlet-chemiexcitation yield comparable with that for a chemically initiated electron exchange luminescence (CIEEL) active dioxetane producing an oxyanion of aromatic ester as an emitter. A 7-siloxynaphthalen-2-yl analog (4b) was found on similar treatment to emit light with the maximum wavelength the longest among CIEEL-active dioxetanes hitherto known. (C) 2003 Elsevier Science Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/S0040-4020(03)00727-0
- ISSN : 0040-4020
- CiNii Articles ID : 80016024524
- Web of Science ID : WOS:000183780900014