2021年
Formate-driven catalysis and mechanism of an iridium–copper complex for selective aerobic oxidation of aromatic olefins in water
Chemical Science
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- 巻
- 12
- 号
- 16
- 開始ページ
- 5796
- 終了ページ
- 5803
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/D0SC06634F
- 出版者・発行元
- Royal Society of Chemistry ({RSC})
A hetero-dinuclear Ir-III-Cu-II complex with two adjacent sites was employed as a catalyst for the aerobic oxidation of aromatic olefins driven by formate in water. An Ir-III-H intermediate, generated through formate dehydrogenation, was revealed to activate terminal aromatic olefins to afford an Ir-alkyl species, and the process was promoted by a hydrophobic [Ir-III-H]-[substrate aromatic ring] interaction in water. The Ir-alkyl species subsequently reacted with dioxygen to yield corresponding methyl ketones and was promoted by the presence of the Cu-II moiety under acidic conditions. The Ir-III-Cu-II complex exhibited cooperative catalysis in the selective aerobic oxidation of olefins to corresponding methyl ketones, as evidenced by no reactivities observed from the corresponding mononuclear Ir-III and Cu-II complexes, as the individual components of the Ir-III-Cu-II complex. The reaction mechanism afforded by the Ir-III-Cu-II complex in the aerobic oxidation was disclosed by a combination of spectroscopic detection of reaction intermediates, kinetic analysis, and theoretical calculations.
- リンク情報
- ID情報
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- DOI : 10.1039/D0SC06634F
- ISSN : 2041-6520
- eISSN : 2041-6539
- ORCIDのPut Code : 90988354
- Web of Science ID : WOS:000631723100001