2019年9月6日
Nickel-Catalyzed Decarbonylative Cyanation of Acyl Chlorides
Organic Letters
- ,
- ,
- ,
- 巻
- 21
- 号
- 17
- 開始ページ
- 6779
- 終了ページ
- 6784
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acs.orglett.9b02398
Copyright © 2019 American Chemical Society. Ni-catalyzed decarbonylative cyanation of acyl chlorides with trimethylsilyl cyanide has been achieved. This transformation is applicable to the synthesis of an array of nitrile compounds bearing a wide range of functional groups under neutral conditions. The step-by-step experimental studies revealed that the reaction sequences of the present catalytic reaction are oxidative addition, transmetalation, decarbonylation, and reductive elimination.
- リンク情報
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- DOI
- https://doi.org/10.1021/acs.orglett.9b02398
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/31389711
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000485089300040&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85070891996&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85070891996&origin=inward
- ID情報
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- DOI : 10.1021/acs.orglett.9b02398
- ISSN : 1523-7060
- eISSN : 1523-7052
- PubMed ID : 31389711
- SCOPUS ID : 85070891996
- Web of Science ID : WOS:000485089300040