MISC

2009年6月

Formation of Continuous Pore Structures in Si-C-O Fibers by Adjusting the Melt Spinning Condition of a Polycarbosilane-Polysiloxane Polymer Blend

JOURNAL OF THE AMERICAN CERAMIC SOCIETY
  • Ken'ichiro Kita
  • ,
  • Masaki Narisawa
  • ,
  • Hiroshi Mabuchi
  • ,
  • Masayoshi Itoh
  • ,
  • Masaki Sugimoto
  • ,
  • Masahito Yoshikawa

92
6
開始ページ
1192
終了ページ
1197
記述言語
英語
掲載種別
DOI
10.1111/j.1551-2916.2009.03053.x
出版者・発行元
WILEY-BLACKWELL PUBLISHING, INC

A polymer blend containing polycarbosilane (PCS) and 15 mass% of polyhydromethylsiloxane (H-oil) was prepared and the properties of the polymer melt were investigated in order to clarify the mechanisms of continuous pore formation. Melt viscosity decreased as the H-oil content increased. Moreover, the saturation of the plasticizer effect of H-oil on the viscosity and apparent turbidity of the melting polymer suggested that the compatibility of H-oil to PCS in melting was limited at 15 mass%. Gas chromatography data after heating showed that an amount of evolved hydrogen at 573 K was increased by 15 mass% of H-oil addition. The fibers formed by the melt-spun of the polymer blend at 578 K mainly possessed a single pore at the center of the fibers' cross section. On the other hand, the fibers melt-spun at 543 K usually included multiple pores, and the fibers melt-spun at 538 K included a number of tiny pores. It is proposed that the evolved hydrogen can be dissolved in the polymer melt, and the desaturation process of the dissolved gas during the fiber spinning with a sudden temperature reduction likely determined the size and location of pores in the fibers.

リンク情報
DOI
https://doi.org/10.1111/j.1551-2916.2009.03053.x
CiNii Articles
http://ci.nii.ac.jp/naid/80020442981
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000266875400004&DestApp=WOS_CPL
ID情報
  • DOI : 10.1111/j.1551-2916.2009.03053.x
  • ISSN : 0002-7820
  • CiNii Articles ID : 80020442981
  • Web of Science ID : WOS:000266875400004

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