Papers

Peer-reviewed
2002

Anion-exchange Behavior of Rf in HCl and HNO3 Solutions

Journal of Nuclear and Radiochemical Sciences
  • H. Haba
  • K. Tsukada
  • M. Asai
  • S. Goto
  • A. Toyoshima
  • I. Nishinaka
  • K. Akiyama
  • M. Hirata
  • S. Ichikawa
  • Y. Nagame
  • Y. Shoji
  • M. Shigekawa
  • T. Koike
  • M. Iwasaki
  • A. Shinohara
  • T. Kaneko
  • T. Maruyama
  • S. Ono
  • H. Kudo
  • Y. Oura
  • K. Sueki
  • H. Nakahara
  • M. Sakama
  • A. Yokoyama
  • J. V. Kratz
  • M. Schaedel
  • W. Bruechle
  • Display all

Volume
3
Number
1
First page
143
Last page
146
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.14494/jnrs2000.3.143
Publisher
The Japan Society of Nuclear and Radiochemical Sciences

A short review is given on our current anion-exchange studies of element 104, rutherfordium (Rf), in HCl and HNO3 solutions. The distribution coefficients of the Rf homologues Zr, Hf, and Th (IV), and Pu (IV) on an anion-exchange resin were measured in 1.0-11.5 M HCl and 1.1-13.1 M HNO3 with a batch method using the radiotracers 88Zr, 175Hf, 234Th, and 237Pu. In experiments for the short-lived 261Rf, the isotopes 85Zr, 169Hf, and 169Rf were produced in the 18O-induced reactions on natGe, 248Gd, and 248Cm targets, respectively, and their anion-exchange behavior in 4.0-11.5 M HCl and 8.0 M HNO3 was investigated using the Automated Ion-exchange separation apparatus coupled with the Detection system for Alpha spectroscopy (AIDA). In the HCl system, the percent adsorption of Rf on the anion-exchange resin increases steeply with increasing HCl concentration from 7.0 M to 11.5 M. This adsorption behavior is similar to that of the group-4 elements Zr and Hf, and is quite different from that of the pseudo-homologue Th (IV). The percent adsorption decreases in the order Rf>Zr>Hf. In the HNO3 system, Rf behaves like Zr and Hf in 8.0 M HNO3 but not like Pu (IV) and Th (IV), implying the formation of cationic or neutral species.

Link information
DOI
https://doi.org/10.14494/jnrs2000.3.143
CiNii Articles
http://ci.nii.ac.jp/naid/10013978312
CiNii Books
http://ci.nii.ac.jp/ncid/AA11948402
URL
https://jlc.jst.go.jp/DN/JALC/00158759393?from=CiNii
ID information
  • DOI : 10.14494/jnrs2000.3.143
  • ISSN : 1345-4749
  • CiNii Articles ID : 10013978312
  • CiNii Books ID : AA11948402

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